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(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
(CAS Number:866081-62-1 Product Number:B5301)

Structure

(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
Synonym (R,R)-QuinoxP*

General Information

Product Number B5301

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Purity/Analysis Method >98.0%(HPLC)
Storage Temperature
M.F. / M.W. C18H28N2P2=334.38
CAS Number 866081-62-1
Related CAS Number
MDL Number MFCD10565649
Packaging and Container 100mg-Plastic Bottle with Glass Insert (View image)
  • Product Details
  • Safety & Regulations

Specification

Purity(HPLC) min. 98.0 area%
Elemental analysis(Nitrogen) 8.00 to 8.80 %
Melting point 100.0 to 104.0 deg-C
Specific rotation [a]20/D -50.0 to -55.0 deg(C=1, CHCL3)

References

Reaxys-RN 10182166

GHS

Pictogram
Signal Word Warning
Hazard Statements
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
  • H413
  • :May cause long lasting harmful effects to aquatic life.
Precautionary Statements
  • P264
  • :Wash hands and face thoroughly after handling.
  • P273
  • :Avoid release to the environment.
  • P280
  • :Wear protective gloves, eye protection.
  • P302+P352+P332+P313+P362+P364
  • :IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. Take off contaminated clothing and wash it before reuse.
  • P305+P351+P338+P337+P313
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.
  • P501
  • :Dispose of contents/container through a waste management company authorized by the local government.

Transport Information

HS Number 2933998090

Application

Dynamic Kinetic Resolution using a Palladium / QuinoxP* Complex

P2161, B5301

References

Copper Catalyzed Asymmetric Conjugate Addition

B5301

References

Rhodium Catalyzed Enantioselective Hydroacylation of Acrylamide Derivatives

B5301

References

Ruthenium Complex Catalyzed Asymmetric Hydrogenation

B5301

References

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