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Silicon Compounds (for Synthesis)

  Silicon is an element belongs to Group 14 of the Periodic Table and thus has properties similar to carbon. A silicon atom can form a σ-bond to a carbon atom and thereby form a variety of organic silicon compounds. However, as carbon belongs to period II and silicon to period III, the two element's atoms differ in atomic size, ionization energy, electronegativity, and atomic orbital configuration amongst other things. These differences cause organic silicon compounds to exhibit characteristic reactivities that are not found in carbon compounds. Silylenol ethers, hydrosilanes, Peterson type reagents, silylcyanides, silyldiazomethane and others are increasingly being used in organic syntheses, not only for their protective moieties, but also as reagents of general interest.
A0729
Allyltrimethylsilane
A0927
Allyloxytrimethylsilane
A1326
Allyl(chloromethyl)dimethylsilane
A1858
Allyltriisopropylsilane
A2298
Allyl(tert-butyl)dimethylsilane
A2299
Allyltriethylsilane
B0511
N,O-Bis(trimethylsilyl)acetamide
B0830
N,O-Bis(trimethylsilyl)trifluoroacetamide
B0995
tert-Butyldimethylchlorosilane [tert-Butyldimethylsilylating Agent]
B1087
Bromotrimethylsilane
B1090
Bis(trimethylsilyl)acetylene
B1103
N,N'-Bis(trimethylsilyl)urea
B1223
tert-Butyldiphenylchlorosilane
B1245
Bis(trimethylsilyl) Sulfate
B1298
1,4-Bis(trimethylsilyl)-1,3-butadiyne
B1302
Bis(trimethylsilyl) Malonate
B1436
tert-Butoxydiphenylchlorosilane (stabilized with CaCO3)
B1654
3-Bromo-1-(trimethylsilyl)-1-propyne
B1663
tert-Butylmethoxyphenylsilyl Bromide
B1688
1,2-Bis(chlorodimethylsilyl)ethane [Protecting Reagent for Primary Amines]
B1695
(2-Bromoallyl)trimethylsilane
B1699
1,2-Bis(dimethylsilyl)benzene
B1728
N-Benzyltrimethylsilylamine
B1768
1,2-Bis(trimethylsilyloxy)cyclobutene
B1769
(1-Bromovinyl)trimethylsilane
B1813
Bis(chloromethyl)dimethylsilane
B1856
Benzyltrimethylsilane
B1857
Bis(trimethylsilyl)methane
B1892
(Bromomethyl)trimethylsilane
B1906
N,O-Bis(tert-butyldimethylsilyl)acetamide [tert-Butyldimethylsilylating Agent]
B2004
Bis(methylthio)(trimethylsilyl)methane
B2334
Benzylchlorodimethylsilane
B2898
tert-Butyldiphenylsilyl Trifluoromethanesulfonate
B3047
3,3'-Bis(trimethylsilyl)biphenyl-4,4'-diyl Bis(trifluoromethanesulfonate)
B3563
1,3-Bis(trimethylsilyloxy)propane
B3565
tert-Butyldimethylsilane
B3566
tert-Butyldiphenylsilane
B3577
tert-Butyl[4-(dimethoxymethyl)phenoxy]dimethylsilane
B3739
4-(tert-Butyldimethylsilyloxy)phenylboronic Acid (contains varying amounts of Anhydride)
C0306
Chlorotrimethylsilane
C0862
(Chloromethyl)trimethylsilane
C1339
2-(Chloromethoxy)ethyltrimethylsilane (stabilized with Diisopropylethylamine)
C1358
Chloromethyl(dichloro)methylsilane
C1370
(Chloromethyl)isopropoxydimethylsilane
C1402
(Chloromethyl)triethoxysilane
C1419
Chloromethyldimethylphenylsilane
C1492
Chlorodiisopropylsilane
C1982
Cyclohexyl(dimethoxy)methylsilane
D0358
Dichlorodimethylsilane
D1147
Chlorodimethylphenylsilane
D1390
Diphenylmethylchlorosilane
D1608
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane [Hydroxyl Protecting Agent]
D1789
Dimethylketene Methyl Trimethylsilyl Acetal
D1825
Methyldiphenylsilane
D2144
1,2-Dichlorotetramethyldisilane
D2196
Dimethylphenylsilane
D2262
Chlorodiethylisopropylsilane
D2403
Diethoxymethylsilane [Hydrosilylating Reagent]
D2406
Diphenylsilane
D2469
Di-tert-butyldichlorosilane
D2820
Diphenylsilane
D2935
2-(Dimethylvinylsilyl)pyridine
D3135
Di-tert-butylsilyl Bis(trifluoromethanesulfonate)
D3386
Dimethoxymethylvinylsilane
D3761
Diethylsilane
D3883
4,5-Dimethoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
E0478
Ethylenedioxybis(trimethylsilane) [Protecting Reagent for Aldehydes and Ketones]
F0518
(1-Fluorovinyl)methyldiphenylsilane
H0089
1,1,1,3,3,3-Hexamethyldisilazane
H0091
Hexamethyldisiloxane
H0638
Hexamethyldisilane
H0893
Potassium Bis(trimethylsilyl)amide (11% in Toluene, ca. 0.5mol/L)
H0894
Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L)
H0915
Lithium Bis(trimethylsilyl)amide (ca. 26% in Tetrahydrofuran, ca. 1.3mol/L)
I0308
Trimethylsilyl Iodide (stabilized with Aluminum)
I0324
Isopropenyloxytrimethylsilane [Trimethylsilylating Agent]
I0449
(Iodomethyl)trimethylsilane
M0450
Trichloro(methyl)silane
M0759
1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene
M1077
N-Methyl-N,O-bis(trimethylsilyl)hydroxylamine
M1264
Methoxymethyltrimethylsilane
M1460
Methylenebis[dimethyl(2-pyridyl)silane]
M1882
4-Methyl-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
M1883
2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate
M1884
3-Methoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
M1885
4-Methoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
P1172
(Phenylthiomethyl)trimethylsilane
P1217
Tris(trimethylsilyl) Phosphite
P1248
Tris(trimethylsilyl) Phosphate
P1250
Phenyl Trimethylsilylmethyl Sulfone
P1280
1-Phenyl-1-trimethylsilyloxyethylene
S0421
Tetraisothiocyanatosilane
T0407
Trichlorovinylsilane
T0492
N-(Trimethylsilyl)diethylamine
T0585
N-Trimethylsilylimidazole [Trimethylsilylating Reagent]
T0590
N-Trimethylsilylacetamide
T0591
N-(Trimethylsilyl)dimethylamine
T0636
Tetrachlorosilane
T0661
Triphenylsilane
T0662
Triethylsilane
T0801
Trimethylsilyl Azide
T0871
Trimethylsilyl Trifluoromethanesulfonate [Trimethylsilylating Agent]
T0939
Triphenylchlorosilane
T1078
Triisopropylsilyl Chloride
T1106
Trimethylsilyl Isocyanate
T1123
1-(Trimethylsilyl)-1-propyne
T1146
Trimethylsilyldiazomethane (ca. 10% in Hexane, ca. 0.6mol/L)
T1184
Trimethylsilylmethyl Azide
T1213
Trimethylsilylmethanethiol
T1239
Trimethylsilylacetylene
T1250
Trimethylsilylmethanol
T1277
N-(Trimethylsilyl)morpholine
T1299
2-Trimethylsilylthiazole
T1334
Trihexylsilane
T1441
2-(Trimethylsilyl)ethanol
T1458
2-(Trimethylsilyl)ethoxymethyltriphenylphosphonium Chloride
T1468
Diethylisopropylsilyl Trifluoromethanesulfonate
T1469
2-Trimethylsilyloxy-1,3-butadiene
T1498
(3-Trimethylsilyl-2-propynyl)triphenylphosphonium Bromide
T1500
3-Trimethylsilyl-2-propyn-1-ol
T1510
(2-Trimethylsilylethyl)triphenylphosphonium Iodide
T1514
2-Trimethylsilyl-1,3-dithiane
T1525
tert-Butyldimethylsilyl Trifluoromethanesulfonate
T1533
Triisopropylsilane
T1535
3-Trimethylsilyl-2-oxazolidinone [Trimethylsilylating Reagent]
T1536
2-(Trimethylsilyloxy)furan
T1556
1-(Trimethylsilyloxy)cyclohexene
T1570
(Trifluoromethyl)trimethylsilane [Trifluoromethylating Reagent]
T1573
4-Trimethylsilyloxy-3-penten-2-one
T1579
(Trimethylsilyl)methyl Trifluoromethanesulfonate [Trimethylsilylmethylating Reagent]
T1584
Ethyl (Trimethylsilyl)acetate
T1588
Triisopropylsilyl Trifluoromethanesulfonate
T1639
Tris(trimethylsilyloxy)ethylene
T1648
1-(Trimethylsilyloxy)cyclopentene
T1689
Triethylsilyl Trifluoromethanesulfonate
T2043
Tributylsilane
T2089
2-(Trimethylsilyl)phenyl Trifluoromethanesulfonate
T2116
Chloro(dimethyl)thexylsilane
T2284
5-(Trimethylsilyl)-1,3-cyclopentadiene
T2465
1-(Trimethylsilyl)-2-naphthyl Trifluoromethanesulfonate
T2466
3-(Trimethylsilyl)-2-naphthyl Trifluoromethanesulfonate
T2467
1,3,5-Tris[4-(trifluoromethanesulfonyloxy)-3-(trimethylsilyl)phenyl]benzene
T2544
2-(Trimethylsilyl)ethyl 3-Nitro-1H-1,2,4-triazole-1-carboxylate
T2746
1-(Trimethylsilyl)-1-pentyne
For other general silicon compounds and GC derivatizing reagents, please refer to "Classes of Silicon Compounds", and "GC Derivatizing Reagents", respectively.
 

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