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Silicon Compounds (for Synthesis)
Silicon is an element belongs to Group 14 of the Periodic Table and thus has properties similar to carbon. A silicon atom can form a σ-bond to a carbon atom and thereby form a variety of organic silicon compounds. However, as carbon belongs to period II and silicon to period III, the two element's atoms differ in atomic size, ionization energy, electronegativity, and atomic orbital configuration amongst other things. These differences cause organic silicon compounds to exhibit characteristic reactivities that are not found in carbon compounds. Silylenol ethers, hydrosilanes, Peterson type reagents, silylcyanides, silyldiazomethane and others are increasingly being used in organic syntheses, not only for their protective moieties, but also as reagents of general interest.
- A0729
- Allyltrimethylsilane
- A0927
- Allyloxytrimethylsilane
- A1326
- Allyl(chloromethyl)dimethylsilane
- A1858
- Allyltriisopropylsilane
- A2298
- Allyl(tert-butyl)dimethylsilane
- A2299
- Allyltriethylsilane
- B0511
- N,O-Bis(trimethylsilyl)acetamide
- B0830
- N,O-Bis(trimethylsilyl)trifluoroacetamide
- B0995
- tert-Butyldimethylchlorosilane [tert-Butyldimethylsilylating Agent]
- B1087
- Bromotrimethylsilane
- B1090
- Bis(trimethylsilyl)acetylene
- B1103
- N,N'-Bis(trimethylsilyl)urea
- B1223
- tert-Butyldiphenylchlorosilane
- B1245
- Bis(trimethylsilyl) Sulfate
- B1298
- 1,4-Bis(trimethylsilyl)-1,3-butadiyne
- B1302
- Bis(trimethylsilyl) Malonate
- B1436
- tert-Butoxydiphenylchlorosilane (stabilized with CaCO3)
- B1654
- 3-Bromo-1-(trimethylsilyl)-1-propyne
- B1663
- tert-Butylmethoxyphenylsilyl Bromide
- B1688
- 1,2-Bis(chlorodimethylsilyl)ethane [Protecting Reagent for Primary Amines]
- B1695
- (2-Bromoallyl)trimethylsilane
- B1699
- 1,2-Bis(dimethylsilyl)benzene
- B1728
- N-Benzyltrimethylsilylamine
- B1768
- 1,2-Bis(trimethylsilyloxy)cyclobutene
- B1769
- (1-Bromovinyl)trimethylsilane
- B1813
- Bis(chloromethyl)dimethylsilane
- B1856
- Benzyltrimethylsilane
- B1857
- Bis(trimethylsilyl)methane
- B1892
- (Bromomethyl)trimethylsilane
- B1906
- N,O-Bis(tert-butyldimethylsilyl)acetamide [tert-Butyldimethylsilylating Agent]
- B2004
- Bis(methylthio)(trimethylsilyl)methane
- B2334
- Benzylchlorodimethylsilane
- B2898
- tert-Butyldiphenylsilyl Trifluoromethanesulfonate
- B3047
- 3,3'-Bis(trimethylsilyl)biphenyl-4,4'-diyl Bis(trifluoromethanesulfonate)
- B3563
- 1,3-Bis(trimethylsilyloxy)propane
- B3565
- tert-Butyldimethylsilane
- B3566
- tert-Butyldiphenylsilane
- B3577
- tert-Butyl[4-(dimethoxymethyl)phenoxy]dimethylsilane
- B3739
- 4-(tert-Butyldimethylsilyloxy)phenylboronic Acid (contains varying amounts of Anhydride)
- C0306
- Chlorotrimethylsilane
- C0862
- (Chloromethyl)trimethylsilane
- C1339
- 2-(Chloromethoxy)ethyltrimethylsilane (stabilized with Diisopropylethylamine)
- C1358
- Chloromethyl(dichloro)methylsilane
- C1370
- (Chloromethyl)isopropoxydimethylsilane
- C1402
- (Chloromethyl)triethoxysilane
- C1419
- Chloromethyldimethylphenylsilane
- C1492
- Chlorodiisopropylsilane
- C1982
- Cyclohexyl(dimethoxy)methylsilane
- D0358
- Dichlorodimethylsilane
- D1147
- Chlorodimethylphenylsilane
- D1390
- Diphenylmethylchlorosilane
- D1608
- 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane [Hydroxyl Protecting Agent]
- D1789
- Dimethylketene Methyl Trimethylsilyl Acetal
- D1825
- Methyldiphenylsilane
- D2144
- 1,2-Dichlorotetramethyldisilane
- D2196
- Dimethylphenylsilane
- D2262
- Chlorodiethylisopropylsilane
- D2403
- Diethoxymethylsilane [Hydrosilylating Reagent]
- D2406
- Diphenylsilane
- D2469
- Di-tert-butyldichlorosilane
- D2820
- Diphenylsilane
- D2935
- 2-(Dimethylvinylsilyl)pyridine
- D3135
- Di-tert-butylsilyl Bis(trifluoromethanesulfonate)
- D3386
- Dimethoxymethylvinylsilane
- D3761
- Diethylsilane
- D3883
- 4,5-Dimethoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
- E0478
- Ethylenedioxybis(trimethylsilane) [Protecting Reagent for Aldehydes and Ketones]
- F0518
- (1-Fluorovinyl)methyldiphenylsilane
- H0089
- 1,1,1,3,3,3-Hexamethyldisilazane
- H0091
- Hexamethyldisiloxane
- H0638
- Hexamethyldisilane
- H0893
- Potassium Bis(trimethylsilyl)amide (11% in Toluene, ca. 0.5mol/L)
- H0894
- Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L)
- H0915
- Lithium Bis(trimethylsilyl)amide (ca. 26% in Tetrahydrofuran, ca. 1.3mol/L)
- I0308
- Trimethylsilyl Iodide (stabilized with Aluminum)
- I0324
- Isopropenyloxytrimethylsilane [Trimethylsilylating Agent]
- I0449
- (Iodomethyl)trimethylsilane
- M0450
- Trichloro(methyl)silane
- M0759
- 1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene
- M1077
- N-Methyl-N,O-bis(trimethylsilyl)hydroxylamine
- M1264
- Methoxymethyltrimethylsilane
- M1460
- Methylenebis[dimethyl(2-pyridyl)silane]
- M1882
- 4-Methyl-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
- M1883
- 2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate
- M1884
- 3-Methoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
- M1885
- 4-Methoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
- P1172
- (Phenylthiomethyl)trimethylsilane
- P1217
- Tris(trimethylsilyl) Phosphite
- P1248
- Tris(trimethylsilyl) Phosphate
- P1250
- Phenyl Trimethylsilylmethyl Sulfone
- P1280
- 1-Phenyl-1-trimethylsilyloxyethylene
- S0421
- Tetraisothiocyanatosilane
- T0407
- Trichlorovinylsilane
- T0492
- N-(Trimethylsilyl)diethylamine
- T0585
- N-Trimethylsilylimidazole [Trimethylsilylating Reagent]
- T0590
- N-Trimethylsilylacetamide
- T0591
- N-(Trimethylsilyl)dimethylamine
- T0636
- Tetrachlorosilane
- T0661
- Triphenylsilane
- T0662
- Triethylsilane
- T0801
- Trimethylsilyl Azide
- T0871
- Trimethylsilyl Trifluoromethanesulfonate [Trimethylsilylating Agent]
- T0939
- Triphenylchlorosilane
- T1078
- Triisopropylsilyl Chloride
- T1106
- Trimethylsilyl Isocyanate
- T1123
- 1-(Trimethylsilyl)-1-propyne
- T1146
- Trimethylsilyldiazomethane (ca. 10% in Hexane, ca. 0.6mol/L)
- T1184
- Trimethylsilylmethyl Azide
- T1213
- Trimethylsilylmethanethiol
- T1239
- Trimethylsilylacetylene
- T1250
- Trimethylsilylmethanol
- T1277
- N-(Trimethylsilyl)morpholine
- T1299
- 2-Trimethylsilylthiazole
- T1334
- Trihexylsilane
- T1441
- 2-(Trimethylsilyl)ethanol
- T1458
- 2-(Trimethylsilyl)ethoxymethyltriphenylphosphonium Chloride
- T1468
- Diethylisopropylsilyl Trifluoromethanesulfonate
- T1469
- 2-Trimethylsilyloxy-1,3-butadiene
- T1498
- (3-Trimethylsilyl-2-propynyl)triphenylphosphonium Bromide
- T1500
- 3-Trimethylsilyl-2-propyn-1-ol
- T1510
- (2-Trimethylsilylethyl)triphenylphosphonium Iodide
- T1514
- 2-Trimethylsilyl-1,3-dithiane
- T1525
- tert-Butyldimethylsilyl Trifluoromethanesulfonate
- T1533
- Triisopropylsilane
- T1535
- 3-Trimethylsilyl-2-oxazolidinone [Trimethylsilylating Reagent]
- T1536
- 2-(Trimethylsilyloxy)furan
- T1556
- 1-(Trimethylsilyloxy)cyclohexene
- T1570
- (Trifluoromethyl)trimethylsilane [Trifluoromethylating Reagent]
- T1573
- 4-Trimethylsilyloxy-3-penten-2-one
- T1579
- (Trimethylsilyl)methyl Trifluoromethanesulfonate [Trimethylsilylmethylating Reagent]
- T1584
- Ethyl (Trimethylsilyl)acetate
- T1588
- Triisopropylsilyl Trifluoromethanesulfonate
- T1639
- Tris(trimethylsilyloxy)ethylene
- T1648
- 1-(Trimethylsilyloxy)cyclopentene
- T1689
- Triethylsilyl Trifluoromethanesulfonate
- T2043
- Tributylsilane
- T2089
- 2-(Trimethylsilyl)phenyl Trifluoromethanesulfonate
- T2116
- Chloro(dimethyl)thexylsilane
- T2284
- 5-(Trimethylsilyl)-1,3-cyclopentadiene
- T2465
- 1-(Trimethylsilyl)-2-naphthyl Trifluoromethanesulfonate
- T2466
- 3-(Trimethylsilyl)-2-naphthyl Trifluoromethanesulfonate
- T2467
- 1,3,5-Tris[4-(trifluoromethanesulfonyloxy)-3-(trimethylsilyl)phenyl]benzene
- T2544
- 2-(Trimethylsilyl)ethyl 3-Nitro-1H-1,2,4-triazole-1-carboxylate
- T2746
- 1-(Trimethylsilyl)-1-pentyne
For other general silicon compounds and GC derivatizing reagents, please refer to "Classes of Silicon Compounds", and "GC Derivatizing Reagents", respectively.











































![tert-Butyl[4-(dimethoxymethyl)phenoxy]dimethylsilane](/image/commodity/B3577.gif)











































![Methylenebis[dimethyl(2-pyridyl)silane]](/image/commodity/M1460.gif)



























































![1,3,5-Tris[4-(trifluoromethanesulfonyloxy)-3-(trimethylsilyl)phenyl]benzene](/image/commodity/T2467.gif)








