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N-Bromosaccharin
(CAS Number:35812-01-2 Product Number:B2152)

Structure

N-Bromosaccharin
Synonym 2-Bromo-1,2-benzisothiazol-3(2H)-one 1,1-Dioxide

General Information

Product Number B2152

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Purity/Analysis Method >98.0%(T)
Storage Temperature 0-10°C
M.F. / M.W. C7H4BrNO3S=262.08
CAS Number 35812-01-2
Related CAS Number
MDL Number MFCD03844772
Packaging and Container
  • Product Details
  • Safety & Regulations

Specification

Purity(Iodometric Titration) min. 98.0 %

References

Reaxys-RN 1213969
PubChem SID 87565018
EC Number 252-737-4

GHS

Pictogram
Signal Word Warning
Hazard Statements
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
Precautionary Statements
  • P264
  • :Wash hands and face thoroughly after handling.
  • P280
  • :Wear protective gloves, eye protection.
  • P302+P352+P332+P313+P362+P364
  • :IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. Take off contaminated clothing and wash it before reuse.
  • P305+P351+P338+P337+P313
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Transport Information

HS Number 2925199590

Application

N-Halosaccharin Usable for Halogenations

Experimental procedure: 1 (142 mg, 0.5 mmol) and LiClO4 (32 mg, 0.3 mmol) are dissolved in CH3CN (10 mL). The reaction mixture is stirred at room temperature for 15 min. N-Bromosaccharin (0.55 mmol) is added and stirring is continued for an additional 30 min. After removal of the solvent, the residue is dissolved in CH2Cl2 (10 mL), washed with strd. aq. NaHCO3 (3 x 10 mL), dried over Na2SO4, filtered and the solvent is evaporated in vacuo. The solid is suspended in CH3OH (4 mL) and, to remove the unwanted saccharin, undissolved pure product is filtered to obtain 2 (114 mg, 63% yield) as a white solid.

References

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