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(1R,4R,5R)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane
（CAS Number：5718-75-2）

Structure

General Information

Product Number	T2578

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Storage Temperature
Purity/Analysis Method	>95.0%(GC)
M.F. / M.W.	C₁₀H₁₈S=170.31
CAS Number	5718-75-2
Related CAS Number
MDL Number
Packaging and Container	1g-Glass Bottle with Plastic Insert

Specification

Purity(GC)	min. 95.0 %
Optical purity(GC)	min. 98.0 ee%
Specific gravity (20/20)	0.9980 to 1.0020
Refractive index n20/D	1.5160 to 1.5200
Specific rotation [a]20/D	-67.0 ～ -73.0deg(C=1.32, CHCl3)

Data of Reference

bp	84°C/5mmHg(Lit.)

References

Beilstein	17(4)212
Reaxys-RN	80225
PubChem SID	125307478

GHS

Signal Word	Warning
Hazard Statements	H227 :Combustible liquid.
Precautionary Statements	P210 :Keep away from flames and hot surfaces. P280 :Wear protective gloves/protective clothing/eye protection/face protection. P403+P235 :Store in a well-ventilated place. Keep cool. P501 :Dispose of contents/container through a waste management company authorized by the local government

Signal Word

Warning

Hazard Statements

H227
:Combustible liquid.

Precautionary Statements

P210
:Keep away from flames and hot surfaces.

P280
:Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235
:Store in a well-ventilated place. Keep cool.

P501
:Dispose of contents/container through a waste management company authorized by the local government

Application

Useful Chiral Auxiliaries for the Synthesis of Chiral Oxiranes

References

1)Practical and highly selective sulfur ylide mediated asymmetric epoxidations and aziridinations using an inexpensive, readily available chiral sulfide
- O. Illa, M. Arshad, A. Ros, E. M. McGarrigle, V. K. Aggarwal, J. Am. Chem. Soc. 2010, 132, 1828.