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CAS RN: 7688-25-7 | Product Number: B1246
1,4-Bis(diphenylphosphino)butane
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Purity: >98.0%(GC)
Synonyms:
- Tetramethylenebis(diphenylphosphine)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 5G |
€38.00
|
1 | ≥100 |
|
| 25G |
€122.00
|
1 | 23 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | B1246 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__2__8H__2__8P__2 = 426.48 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 7688-25-7 |
| Reaxys Registry Number | 706446 |
| PubChem Substance ID | 87564182 |
| SDBS (AIST Spectral DB) | 18417 |
| MDL Number | MFCD00003051 |
Specifications
| Appearance | White to Almost white powder to crystaline |
| Purity(GC) | min. 98.0 % |
| Purity(Iodometric Titration) | min. 95.0 % |
| Melting point | 133.0 to 137.0 °C |
Properties (reference)
| Melting Point | 134 °C |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
| EC Number | 231-698-7 |
Transport Information:
| HS Number | 2931499090 |
Application
Rhodium-Catalyzed Cross-coupling of Organoboron Compounds with Vinyl Acetate
Typical procedure: Under nitrogen atmosphere, a mixture of an arylboron compounds (0.50 mmol), [RhCl(cod)]2 (6.2 mg, 13 µmol), DPPB (11.7 mg, 28 µmol), and K3PO4 (320 mg, 1.5 mmol) is diluted with toluene (2.0 mL). Alkenyl acetate (1.1 or 2.5 mmol) and tert-amyl alcohol (0.55-1.5 mmol) are added into the resulting suspension at room temperature. The mixture is stirred at 100℃ for 24 h and then diluted with hexane (2.0 mL) or EtOAc (2.0 mL). After the filtration through a Celite pad, solvent is removed from the filtrate under reduced pressure. The residue is purified with a flash column chromatography (EtOAc-hexane) to give the desired product.
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