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CAS RN: 1372124-90-7 | Product Number: D5498
1,3-Diisopropylimidazolium Hydrogencarbonate (contains varying amounts of 1,3-Diisopropylimidazolium-2-carboxylate)

Purity:
Synonyms:
- [IiPr(H)][HCO3] (contains varying amounts of 1,3-Diisopropylimidazolium-2-carboxylate)
Product Documents:
Size | Unit Price | Belgium | Japan* | Quantity |
---|---|---|---|---|
1G |
€271.00
|
1 | ≥60 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Product Number | D5498 |
Molecular Formula / Molecular Weight | C__1__0H__1__8N__2O__3 = 214.27 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Moisture Sensitive |
CAS RN | 1372124-90-7 |
Related CAS RN | 1173202-02-2 |
Reaxys Registry Number | 19785609 |
PubChem Substance ID | 354335708 |
Specifications
Appearance | White to Light yellow to Light orange powder to crystal |
Purity(HPLC) | min. 98.0 area% |
Purity(Nonaqueous Titration) | 97.0 to 103.0 % |
Properties (reference)
GHS
Pictogram |
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Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
HS Number | 2933299090 |
Application
NHC Hydrogencarbonate Salts: Transition metal / NHC complex catalyst preparation
(CH3)2SAuCl (11.4 mg), NHC hydrogen carbonate salt (1.2 eq.), and THF (0.7 mL) are put in a capped vial (air atmosphere). After 1 h of stirring at 50 °C, the solution is filtered over silica and dried in vacuo. The Au-NHC complex is obtained as a colorless solid in 95% yield.
References
- Imidazol(in)ium Hydrogen Carbonates as a Genuine Source of N-Heterocyclic Carbenes (NHCs): Applications to the Facile Preparation of NHC Metal Complexes and to NHC-Organocatalyzed Molecular and Macromolecular Syntheses
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