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CAS RN: 16949-15-8 | Product Number: L0186
Lithium Borohydride (ca. 4mol/L in Tetrahydrofuran)
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Purity:
Synonyms:
- Lithium Tetrahydridoborate (ca. 4mol/L in Tetrahydrofuran)
- Lithium Tetrahydroborate (ca. 4mol/L in Tetrahydrofuran)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 100ML |
€479.00
|
1 | ≥100 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
100mL bottle of this product is attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| Product Number | L0186 |
| Molecular Formula / Molecular Weight | H__4BLi = 21.78 |
| Physical State (20 deg.C) | Liquid |
Storage Temperature 
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| Packaging and Container
|
100ML-DualSeal Bottle (View image) |
| CAS RN | 16949-15-8 |
| Reaxys Registry Number | 11536633 |
| PubChem Substance ID | 87558580 |
| Merck Index (14) | 5525 |
Specifications
| Appearance | Colorless to Brown clear liquid to cloudy liquid |
| Concentration(Gasburet method) | 9.5 to 11.5 w/w% |
| NMR | confirm to structure |
Properties (reference)
| Flash point | -18 °C |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. H371 : May cause damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H351 : Suspected of causing cancer. H335 : May cause respiratory irritation. H225 : Highly flammable liquid and vapour. H260 : In contact with water releases flammable gases which may ignite spontaneously. |
| Precautionary Statements | P231 + P232 : Handle and store contents under inert gas. Protect from moisture. P260 : Do not breathe mist or vapours. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P302 + P335 + P334 : IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 241-021-7 |
Transport Information:
| UN Number | UN3399 |
| Class | 4.3 / 3 |
| Packing Group | I |
| HS Number | 2850002090 |
Application
Reducing Agent
References
- Mixed solvents containing methanol as useful reaction media for unique chemoselective reductions within lithium borohydride
- Improved procedure for the reduction of N-acyloxazolidinones
- Regiospecific reduction of 5-benzylidene-2,4-thiazolidinediones and 4-oxo-2-thiazolidinethiones using lithium borohydride in pyridine and tetrahydrofuran
Application
Inorganic Hydride Used as A Hydrogen Sources of Fuel Cell
References
- Development of hydrogen storage for fuel cell generators. I: Hydrogen generation using hydrolysis of hydrides
- Hydrogen generation from hydrides in millimeter scale reactors for micro proton exchange membrane fuel cell applications
- Hydrogen desorption from LiBH4 destabilized by chlorides of transition metal Fe, Co, and Ni
PubMed Literature
Please visit the Pubchem page at this link.
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