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CAS RN: 26456-05-3 | Product Number: M1787

10-Methylacridinium Perchlorate


Purity: >98.0%(N)
Synonyms:
Documents:
250MG
A$211.00
18   1  
1G
A$456.00
13   16  
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Product Number M1787
Purity / Analysis Method >98.0%(N)
Molecular Formula / Molecular Weight C__1__4H__1__2ClNO__4 = 293.70  
Physical State (20 deg.C) Solid
CAS RN 26456-05-3
Reaxys Registry Number 3647072
PubChem Substance ID 87559032
Specifications
Appearance Light yellow to Amber to Dark green powder to crystal
Purity(with Total Nitrogen) min. 98.0 %
Properties (reference)
Melting Point 241 °C(dec.)
GHS
Pictogram Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H272 : May intensify fire
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P220 : Keep/Store away from clothing/ combustible materials.
P210 : Keep away from heat.
P221 : Take any precaution to avoid mixing with combustibles.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
UN Number UN1479
Class 5.1
Packing Group III
H.S.code* 2933.99-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Baeyer–Villiger Oxidation with 10-Methylacridinium as an Organocatalyst

Typical Procedure:
Cyclobutanone (0.5 mmol) and 10-methylacridinium perchlorate (7.4 mg, 0.025 mmol) are dissolved in CH3CN (1 mL). Hydrogen peroxide (68 µL, 30% solution in water, 0.6 mmol) is added and the mixture is irradiated with a 450 W high-pressure mercury lamp in a Pyrex® flask (λ>320 nm) at room temperature for 20 h. The course of the reaction is monitored by TLC. After completion of the reaction, solvent is evaporated in vacuum. Purification of the residue by column chromatography (silica gel, ethyl acetate/petroleum ether gradient) yields the corresponding lactone.

References


PubMed Literature


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