CAS RN: 119812-51-0 | Product Number: P1235
Phthalimide DBU Salt
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|Purity / Analysis Method||>98.0%(T)|
|Molecular Formula / Molecular Weight||C__1__7H__2__1N__3O__2 = 299.37|
|Physical State (20 deg.C)||Solid|
|Store Under Inert Gas||Store under inert gas|
|Condition to Avoid||Hygroscopic|
|Reaxys Registry Number||4343711|
|PubChem Substance ID||87575331|
|Appearance||White to Almost white powder to crystal|
|Purity(Nonaqueous Titration)||min. 98.0 %|
|Melting Point||142 °C|
|Hazard Statements||H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
|Precautionary Statements||P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
A solution of 1 (11.0 g, 63.9 mmol) in dichloromethane (50 mL) is added dropwise over a period of 1 h, to a cold (0 °C) solution of 2 (15.0 g, 51.0 mmol) dissolved in dichloromethane (200 mL). After additional 2 h at 0 °C the reaction mixture is washed with ice-cold 1 mol/L H2SO4 (3 x 100 mL) and water (100 mL). After being dried over MgSO4, the solution is concentrated to a yellow oil (14.4 g) at reduced pressure. The oil is further dried on an oil pump after which addition of diethyl ether (200 mL) gives a precipitate of 4 after the solution has been allowed to stand for 3 days at -18 °C. The yield is 3.40 g (21%). The mother liquid is purified by flash chromatography (diethyl ether:hexane = 7:3) to give 3 (6.11 g, 30% yield).
- Synthesis and Evaluation of Antiviral Activity of L-Acosamine and L-Ristosamine Nucleosides of Furanose Configuration
- Michael-type additions to α,β-unsaturated aldehydes
- J. Wengel, J. Lau, E. B. Pedersen, Synthesis 1989, 829.
- H. Petersen, M. S. Motawia, E. S. Andreassen, J. P. Jacobsen, E. B. Pedersen, Chem. Scr. 1988, 28, 341.
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