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CAS RN: 1032768-06-1 | Product Number: B4643

sec-Butylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca. 1.2mol/L)


Purity:
Synonyms:
  • 2-Butylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca. 1.2mol/L)
Documents:
100ML
€89.00
1   3  

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Product Number B4643
Molecular Formula / Molecular Weight C__4H__9ClMg·LiCl = 159.26  
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 1032768-06-1
Reaxys Registry Number 18893903
PubChem Substance ID 253662605
Specifications
Concentration(sec Butanol method) 15.0 to 19.0 w/w%
Properties (reference)
Boiling Point 66 °C/1.0 mmHg
Flash point -21 °C
GHS
Pictogram Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
H371 : May cause damage to organs.
H372 : Causes damage to organs through prolonged or repeated exposure.
H351 : Suspected of causing cancer.
H335 : May cause respiratory irritation.
H225 : Highly flammable liquid and vapour.
H260 : In contact with water releases flammable gases which may ignite spontaneously.
Precautionary Statements P260 : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P231 + P232 : Handle and store contents under inert gas. Protect from moisture.
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P302 + P335 + P334 : IF ON SKIN: Brush off loose particles from skin. Immerse in cool water.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws:
Transport Information:
UN Number UN3399
Class 4.3 / 3
Packing Group I
HS Number 2931399090
Application
Turbo Grignard Reagent
References

Selective Mono- and 1,2-Difunctionalisation of Cyclopentene Derivatives via Mg and Cu Intermediates

C. Despotopoulou, R. C. Bauer, A. Krasovskiy, P. Mayer, J. M. Stryker, P. Knochel, Chem. Eur. J. 2008, 14, 2499.


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