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CAS RN: 1032768-06-1 | Product Number: B4643

sec-Butylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca. 1.2mol/L)

  • 2-Butylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca. 1.2mol/L)
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Product Number B4643
Molecular Formula / Molecular Weight C__4H__9ClMg·LiCl = 159.26  
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 1032768-06-1
Reaxys Registry Number 18893903
PubChem Substance ID 253662605
Concentration(sec Butanol method) 15.0 to 19.0 w/w%
Properties (reference)
Boiling Point 66 °C/1.0 mmHg
Flash point -21 °C
Pictogram Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
H371 : May cause damage to organs.
H372 : Causes damage to organs through prolonged or repeated exposure.
H351 : Suspected of causing cancer.
H335 : May cause respiratory irritation.
H225 : Highly flammable liquid and vapour.
H260 : In contact with water releases flammable gases which may ignite spontaneously.
Precautionary Statements P260 : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P231 + P232 : Handle and store contents under inert gas. Protect from moisture.
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P302 + P335 + P334 : IF ON SKIN: Brush off loose particles from skin. Immerse in cool water.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws:
Transport Information:
UN Number UN3399
Class 4.3 / 3
Packing Group I
HS Number 2931399090
Turbo Grignard Reagent

Selective Mono- and 1,2-Difunctionalisation of Cyclopentene Derivatives via Mg and Cu Intermediates

C. Despotopoulou, R. C. Bauer, A. Krasovskiy, P. Mayer, J. M. Stryker, P. Knochel, Chem. Eur. J. 2008, 14, 2499.

PubMed Literature


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