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CAS RN: 917604-39-8 | Product Number: B5603

1,3-Bis(2,6-diisopropylphenyl)imidazolium-2-carboxylate


Purity: >98.0%(T)(HPLC)
Synonyms:
  • IPr·CO2
Documents:
1G
€105.00
2   ≥20 

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Product Number B5603
Purity / Analysis Method >98.0%(T)(HPLC)
Molecular Formula / Molecular Weight C__2__8H__3__6N__2O__2 = 432.61  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Hygroscopic
CAS RN 917604-39-8
Reaxys Registry Number 9656270
PubChem Substance ID 354335706
Specifications
Appearance White to Almost white powder to crystal
Purity(HPLC) min. 98.0 area%
Purity(Nonaqueous Titration) min. 98.0 %
Properties (reference)
Melting Point 198 °C(dec.)
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
HS Number 2933299090
Application
Gold Surface Modification with N-Heterocyclic Carbene
References

Ballbot-type motion of N-heterocyclic carbenes on gold surfaces

G. Wang, A. Rühling, S. Amirjalayer, M. Knor, J. B. Ernst, C. Richter, H.-J. Gao, A. Timmer, H.-Y. Gao, N. L. Doltsinis, F. Glorius, H. Fuchs, Nat. Chem. 2017, 9, 152.


Application
NHC-CO2 Adducts: Transition Metal / NHC Complex Catalyst Preparation

A mixture of [Rh(cod)Cl]2 (54 mg) and NHC-CO2 adduct (2 eq.) is stirred in acetonitrile (3 ml) for 5 min at room temperature in a Schlenk flask, followed by heating at 75 °C for 20 min under an atmosphere of argon. The reaction mixture is dried in vacuo, and washed three times with diethyl ether. The yellow solid obtained is analytically pure (93%).

References


Application
Conjugate Cyanation using NHC-CO2 Adducts as a Precursor to NHC Catalysts
References

N-Heterocyclic Carbene Catalyzed 1,6-Conjugate Addition of Me3Si-CN to para-Quinone Methides and Fuchsones: Access to α-Arylated Nitriles

P. Goswami, G. Singh, R. V. Anand, Org. Lett. 2017, 19, 1982.


PubMed Literature


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