Maintenance Notice (4:00 AM November 1 - 9:30 AM November 1, 2025): This website is scheduled to be unavailable due to maintenance. We appreciate your patience and understanding.
Published TCIMAIL newest issue No.199
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 492-08-0 | Product Number: S0884
(+)-Sparteine
×
![]()
×
Purity: >98.0%(GC)
Synonyms:
- Pachycarpine
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
€103.00
|
8 | 18 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | S0884 |
Purity / Analysis Method 
|
>98.0%(GC) |
| Molecular Formula / Molecular Weight | C__1__5H__2__6N__2 = 234.39 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Heat Sensitive |
| CAS RN | 492-08-0 |
| Reaxys Registry Number | 82448 |
| PubChem Substance ID | 160871001 |
| MDL Number | MFCD00869353 |
Specifications
| Appearance | Colorless to Light orange to Yellow clear liquid |
| Purity(GC) | min. 98.0 % |
| Optical purity(GC) | min. 99.0 ee% |
| NMR | confirm to structure |
Properties (reference)
| Boiling Point | 174 °C/8 mmHg |
| Flash point | 148 °C |
| Specific Rotation | 18° (C=1,EtOH) |
| Refractive Index | 1.53 |
| Maximum Absorption Wavelength | 202 nm (CH__3CN) |
| Solubility (slightly sol. in) | Ethanol |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P270 : Do not eat, drink or smoke when using this product. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. |
Related Laws:
| RTECS# | RT0620000 |
Transport Information:
| HS Number | 2939799090 |
Application
Sparteines as Chiral Ligands for Asymmetric Synthesis
References
- 1)Review of (?)-sparteine as a chiral ligand for metal catalysts
- 2)Review of enantioselective synthesis with Li/(?)-sparteine carbanion pairs
- 3)Asymmetric lithiation of (?)-sparteine and (+)-sparteine
- 4)Asymmetric aldol additions using (?)-sparteine and TiCl4
- 5)Palladium-catalyzed oxidative kinetic resolutions of secondary alcohols with (?)-sparteine
- 6)Enantiomer-selective polymerizations using (?)-sparteine
Application
Total Synthesis of (+)-Sparteine
References
- First Asymmetric Total Synthesis of (+)-Sparteine
- Asymmetric total synthesis of (+)-sparteine and the synthesis of a readily accessible (+)-sparteine surrogate
- R. Iyengar, V. Gracias, Chemtracts 2004, 17, 92.
PubMed Literature
Documents
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.