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Published TCIMAIL newest issue No.199
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CAS RN: 593-60-2 | Product Number: V0127
Vinyl Bromide (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L)
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Purity:
Synonyms:
- Bromoethylene (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 100ML |
€71.00
|
13 | ≥40 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Supplemental Product Information:
100mL bottle of this product is attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| Product Number | V0127 |
| Molecular Formula / Molecular Weight | C__2H__3Br = 106.95 |
| Physical State (20 deg.C) | Liquid |
Storage Temperature 
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Heat Sensitive |
| Packaging and Container
|
100ML-DualSeal Bottle (View image) |
| CAS RN | 593-60-2 |
| Reaxys Registry Number | 1361370 |
| PubChem Substance ID | 253661892 |
| MDL Number | MFCD00000183 |
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Concentration(HNMR) | 11.5 to 12.5 w/w% |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H371 : May cause damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H341 : Suspected of causing genetic defects. H350 : May cause cancer. H335 : May cause respiratory irritation. H225 : Highly flammable liquid and vapour. |
| Precautionary Statements | P260 : Do not breathe mist or vapours. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P201 : Obtain special instructions before use. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 209-800-6 |
Transport Information:
| UN Number | UN1993 |
| Class | 3 |
| Packing Group | II |
| HS Number | 2903691950 |
Application
Enamide synthesis via cross-coupling
Application: To a screw-cap vial are added 1 (1.0 eq.), vinyl bromide (1.0 M soln. in THF, 2.0 eq.), CuI (0.05 eq.), N,N’-dimethylethylenediamine (0.10 eq.), and K2CO3 (2.0 eq.). The vial is tightly sealed and heated to 80 °C to stir overnight. Upon completion of the reaction, the mixture is filtered through a pad of celite, rinsing with EtOAc, and solvent is removed in vacuo to afford a crude product. Purification of the resulting crude residue via silica gel flash chromatography (gradient elution: EtOAc in n-hexanes) affords 2 (58% yield) as a yellow solid.
References
- Enamide-Benzyne-[2 + 2] Cycloaddition: Stereoselective Tandem [2 + 2] – Pericyclic Ring-Opening – Intramolecular N-Tethered [4 + 2] Cycloadditions
PubMed Literature
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Other Documents
Related Products
Vinyl Bromide (ca. 14% in Ethyl Ether, ca. 1.0mol/L)
| Product # | V0126 |
| CAS RN | 593-60-2 |
| Purity / Analysis Method: |