Published TCIMAIL newest issue No.197
Maximum quantity allowed is 999
Merci de sélectionner la quantité
CAACs (Cyclic Alkyl Amino Carbenes) have been developed by the Bertrand group as an alternative cyclic carbene species to that of of NHCs (N-Heterocyclic carbenes).1) CAACs are analogs of NHCs in which the one of the key nitrogens has been replaced with an electron-rich carbon atom. As a result, the CAACs' carbene carbon behaves as a strong σ donnor.2) CAACs are able to coordinate to not only transition metals but also non-transition metals and boron. The unique reactivity of those complexes have been reported in recent years and is an area of active research.3-10)
Product
References
- 1)Stable Cyclic (Alkyl)(amino)carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom Makes the Difference V.
- 2)Cyclic (alkyl)(amino)carbene Gold(I) Complexes: A Synthetic and Structural Investigation
- 3)Cyclic (Alkyl)(amino)carbenes (CAACs): Stable Carbenes on the Rise
- 4)Group 1 and 2 Cyclic (alkyl)(amino)carbene Complexes
- 5)Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines
- 6)Building a Lewis Base with Boron
- 7)Nitrogen fixation and reduction at boron
- 8)Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes
- 9)Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes
- 10)Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis