Published TCIMAIL newest issue No.199
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 80049-61-2 | Product Number: T3079
Tris(acetonitrile)cyclopentadienylruthenium(II) Hexafluorophosphate
×
![]()
×
Purity:
Synonyms:
- [CpRu(MeCN)3]PF6
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 200MG |
125,00 €
|
1 | ≥100 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
| Product Number | T3079 |
| Molecular Formula / Molecular Weight | C__1__1H__1__4F__6N__3PRu = 434.29 |
| Physical State (20 deg.C) | Solid |
Storage Temperature 
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Heat Sensitive |
| CAS RN | 80049-61-2 |
| Reaxys Registry Number | 14432805 |
| PubChem Substance ID | 253661000 |
| MDL Number | MFCD02684569 |
Specifications
| Appearance | Light yellow to Brown powder to crystal |
| Elemental analysis(Nitrogen) | 8.70 to 10.10 % |
Properties (reference)
| Melting Point | 149 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P261 : Avoid breathing dust. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
Related Laws:
Transport Information:
| HS Number | 2843909000 |
Application
An anti-Markovnikov Hydration Reaction of Terminal Alkynes Using Ruthenium Complexes
Representative procedure for the hydration: A 4 mL vial is charged sequentially with 5,5’-bis(trifluoromethyl)-2,2’-bipyridine (2, 2.9 mg, 10 µmol, 0.020 eq.), tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate (1, 4.4 mg, 10 µmol, 0.020 eq.), a mixture of water/N-methyl-2-pyrrolidinone (1:4 v/v, 2.5 mL, deoxygenated by sparging with nitrogen), and (2-fluorophenyl)acetylene (60.0 mg, 500 µmol, 1 eq.). The vial is sealed with a Teflon-lined cap. The mixture is stirred for 8 h at 25 ℃. The product mixture is transferred to a separatory funnel and diluted with ethyl acetate (20 mL). The organic layer is washed with brine (3 x 20 mL). The ethyl acetate layer is concentrated. The residue obtained is purified by flash-column chromatography (eluting with 1 % ethyl acetate–hexanes - 2 % ethyl acetate-hexanes) to provide (2-fluorophenyl)acetaldehyde as a clear, colorless oil (56.6 mg,82%).
References
- Broad-Spectrum Catalysts for the Ambient Temperature Anti-Markovnikov Hydration of Alkynes
PubMed Literature
Documents
Product Articles
[Research Articles] An anti-Markovnikov Hydration Reaction of Terminal Alkynes Using Ruthenium ComplexesProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.