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膦类 [化学结构分类]

 Phosphorus belongs to group 15 in the periodic table, the same as nitrogen, and it binds with carbon to form various organophosphate compounds. However, since nitrogen belongs to the second-period and phosphorus to the third, they differ in atomic size, ionization energy and electronegativity etc. Therefore, organophosphate compounds show a characteristic reactivity which organic nitrogen compounds do not have, and it is utilized as a versatile reaction reagent in organic synthesis. For example, phosphorus has a high affinity for oxygen: phosphorus ylide and phosphonate are utilized for the Wittig reaction and the Horner-Emmons reaction, respectively, and it extracts oxygen from aldehydes to produce olefins. Phosphine extracts oxygen from alcohols to produce esters in the Mitsunobu reaction.
 Another feature of phosphine includes bearing a soft lone pair. Therefore, it forms comparatively stable complexes with transition metals such as palladium. This transition metal complex is used frequently as a catalyst in reactions such as the Suzuki-Miyaura cross-coupling reaction and the Heck reaction.1) Although phosphine also has a trigonal pyramidal structure like amines, its rotational barrier energy is considerably higher than the corresponding amine. Therefore, a phosphine which has three different substituents has optical isomers. This optically-active phosphine is utilized for asymmetric syntheses as a P-chiral ligand.2) In this section, we introduce tri-substituted alkyl and aryl phosphines, such as tricyclohexylphosphine and triphenylphosphine.

Literature

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产品编码 X0070
CAS RN 137219-86-4
纯度/分析方法 >97.0%(HPLC)

产品编码 V0132
CAS RN 384842-25-5
纯度/分析方法 >98.0%(HPLC)

产品编码 T1024
CAS RN 6163-58-2
纯度/分析方法 >97.0%(GC)

产品编码 T1757
CAS RN 3053-68-7
纯度/分析方法 >97.0%(T)

产品编码 C1429
CAS RN 6372-42-5
纯度/分析方法 >97.0%(GC)

产品编码 D1019
CAS RN 1605-53-4
纯度/分析方法 >97.0%(GC)(T)

产品编码 D3388
CAS RN 247940-06-3
纯度/分析方法 >98.0%(GC)

产品编码 B1960
CAS RN 27721-02-4
纯度/分析方法 >96.0%(GC)(T)

产品编码 B1405
CAS RN 76189-56-5
纯度/分析方法

产品编码 D3389
CAS RN 213697-53-1
纯度/分析方法 >98.0%(GC)(T)

产品编码 B3196
CAS RN 136274-57-2
纯度/分析方法 >98.0%(T)

产品编码:   X0070 | 纯度/分析方法   >97.0%(HPLC)

产品编码:   V0132 | 纯度/分析方法   >98.0%(HPLC)

产品编码:   T1024 | 纯度/分析方法   >97.0%(GC)

产品编码:   T1757 | 纯度/分析方法   >97.0%(T)

产品编码:   C1429 | 纯度/分析方法   >97.0%(GC)

产品编码:   D1019 | 纯度/分析方法   >97.0%(GC)(T)

产品编码:   D3388 | 纯度/分析方法   >98.0%(GC)

产品编码:   B1960 | 纯度/分析方法   >96.0%(GC)(T)

产品编码:   B1405 | 纯度/分析方法  

产品编码:   D3389 | 纯度/分析方法   >98.0%(GC)(T)

产品编码:   B3196 | 纯度/分析方法   >98.0%(T)