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Rhodium Catalyst for cis-Selective Hydrogenation of Aromatic Rings

CAAC (Cyclic(Amino)(Alkyl)Carbene)-rhodium complexes are used as efficient and selective aromatic hydrogenation catalysts owning from their strongly σ-donating ligands. These catalysts can be used for the synthesis of cyclohexane moieties while still retaining various functional groups like carbonyls, silyls, and boryls in a single step. Under these conditions, the cis-configured saturated hydrocarbon is selectively given.

Rhodium Catalyst for cis-Selective Hydrogenation of Aromatic Rings

Product

C3592
(Cyclohexyl-CAAC)Rh(COD)Cl
(= Chloro[2-(2,6-diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]dec-1- ylidene]-
[1,2,5,6-η-1,5-cyclooctadiene]rhodium)

Advantages

• Utilized in selective hydrogenation of aromatic rings in aromatic ketones
• Suitable for the conversion of phenols to cyclohexanones
• Effective in cis-selective hydrogenation of multisubstituted aromatic compounds

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Applications

hydrogenation catalyzed by C3592

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Related Product

D5596
Cyclohexyl-CAAC
(=2-(2,6-Diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]dec-1-en-2-ium
Hydrogen Dichloride)

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Related Product Category Page

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Product Brochure

Rhodium Catalyst for cis-Selective Hydrogenation of Aromatic Rings (PDF)

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References

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