Hara试剂: 一种新型的稳定并且易于操作的氟化试剂

关键词

P2140

IF₅-Pyridine-HF

(*This product is discontinued.)

文献

• 1) IF₅–pyridine–HF: air- and moisture-stable fluorination reagent
  • S. Hara, M. Monoi, R. Umemura, C. Fuse, Tetrahedron 2012, 68, 10145.
• 2) Synthesis of fluoromethyl ethers and fluoromethyl esters by the reaction of the corresponding methylthiomethyl ethers and methylthiomethyl esters with IF₅-pyridine-HF
  • M. Kunigami, S. Hara, J. Fluorine Chem. 2014, 167, 101.
• 3) Synthesis of trifluoromethyl ethers and difluoro(methylthio)methyl ethers by the reaction of dithiocarbonates with IF₅-pyridine-HF
  • T. Inoue, C. Fuse, S. Hara, J. Fluorine Chem. 2015, 179, 48.
• 4) Synthesis of glycosyl fluorides from (phenylthio)glycosides using IF₅-pyridine-HF
  • M. Kunigami, S. Hara, Carbohydr. Res. 2015, 417, 78.
• 5) Iodofluorination of Alkenes Using IF₅–Pyridine–HF
  • S. Yano, S. Hara, Synthesis 2015, 2839.
• 6) Iodoazidation of Alkenes by Using Iodine Pentafluoride-Pyridine-Hydrogen Fluoride and Trimethylsilyl Azide
  • T. Hiraoka, S. Yano, S. Hara, Synthesis 2016, 48, 1353.
• 7) Stereoselective synthesis of iodofluoroalkenes by iodofluorination of alkynes using IF₅-pyridine-HF
  • H. Ukigai, S. Hara, Tetrahedron Lett. 2016, 57, 1379.
• 8) Trifluorination of sulfides and dithioketals using IF₅-pyridine-HF
  • T. Inoue, S. Nakabo, S. Hara, J. Fluorine Chem. 2016, 184, 22.

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