Easy-to-Handle Trifluoromethylating Agent for Multiple Uses

5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

Product

T4037: 5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

This product is manufactured pursuant to a license with Studiengesellschaft Kohle gGmbH.
This product is intended to be used for research and development purposes only. If you need to order for commercial use or larger quantities, please contact us.

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Advantages

Air-stable and easy-to-handle solid powder
Highly reactive in a wide range of reactions

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Applications ^1,2)

Cross-Coupling Reaction

Nucleophilic Trifluoromethylation

Trifluoromethylation of Thiols

Radical Trifluoromethylation

Electrophilic Trifluoromethylation

Hydrotrifluoromethylation of Olefins

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References

1) Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF₃⁺, CF₃^•, and CF₃^– Reactivity
- H. Jia, T. Ritter, et. al., J. Am. Chem. Soc. 2021, 143, 7623.
2) α-Thianthrenium Carbonyl Species: The Equivalent of an α-Carbonyl Carbocation
- H. Jia, T. Ritter, Angew. Chem. Int. Ed. 2022, 61, e202208978.

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Related Product Category Pages

Trifluoromethylation [Synthetic Reagents]

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Product Brochure

Easy-to-Handle Trifluoromethylating Agent for Multiple Uses (PDF file)

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Easy-to-Handle Trifluoromethylating Agent for Multiple Uses

Product

Advantages