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CAS RN: 87269-87-2 | Product Number: B5344
Benzyl (S,S,S)-2-Azabicyclo[3.3.0]octane-3-carboxylate Hydrochloride
![Thumbnail of Benzyl (S,S,S)-2-Azabicyclo[3.3.0]octane-3-carboxylate Hydrochloride](/medias/B5344.jpg?context=bWFzdGVyfHJvb3R8MTUwNDB8aW1hZ2UvanBlZ3xhR05pTDJneVpDODRPVE16TnprM01qWTFORE00TDBJMU16UTBMbXB3Wnd8ZmE3OTNiYzczYjkxNWM3MzhkMzhiMWY1MzViZDYzM2Q4NGU2MjYwNGE3ZTQ3M2MwYmZjYzI0NDBhODRiMjViZQ "Benzyl (S,S,S)-2-Azabicyclo[3.3.0]octane-3-carboxylate Hydrochloride")
![Chemical Structure of Benzyl (S,S,S)-2-Azabicyclo[3.3.0]octane-3-carboxylate Hydrochloride](/medias/B5344.jpg?context=bWFzdGVyfHJvb3R8NDg1MjF8aW1hZ2UvanBlZ3xhRFUzTDJneU15ODRPVEl3TXpnek5EZzRNRE13TDBJMU16UTBMbXB3Wnd8M2Y0YTAyNWJhMmJmNjBhMDdhYzEwZjFkMDY1MTJhMGQxMGEyMWU5ODgwZWExNzExNjk0MDdjZWNhZmM2MGRlYQ "Benzyl (S,S,S)-2-Azabicyclo[3.3.0]octane-3-carboxylate Hydrochloride")
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![Benzyl (S,S,S)-2-Azabicyclo[3.3.0]octane-3-carboxylate Hydrochloride](/_ui/responsive/theme-tci/images/missing_product_zoom.webp "Benzyl (S,S,S)-2-Azabicyclo[3.3.0]octane-3-carboxylate Hydrochloride")
Purity: >98.0%(T)(HPLC)
Synonyms:
- (S,S,S)-2-Azabicyclo[3.3.0]octane-3-carboxylic Acid Benzyl Ester Hydrochloride
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
38,00 €
|
Contact Us | 1 |
|
|
| 5G |
178,00 €
|
1 | 14 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
| Product Number | B5344 |
Purity / Analysis Method 
|
>98.0%(T)(HPLC) |
| Molecular Formula / Molecular Weight | C__1__5H__1__9NO__2·HCl = 281.78 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 87269-87-2 |
| Reaxys Registry Number | 3636474 |
| PubChem Substance ID | 354334662 |
| MDL Number | MFCD04974076 |
Specifications
| Appearance | White to Orange to Green powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Purity(Argentometric Titration) | min. 98.0 % |
| Specific rotation [a]20/D | -28.0 to -32.0 deg(C=1, DMSO) |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 181 °C |
| Specific Rotation | -31° (C=1,DMSO) |
| Solubility (soluble in) | Methanol |
GHS
Related Laws:
Transport Information:
| HS Number | 2933998090 |
Application
A Synthetic Intermediate of Ramipril
This reagent is used for the synthesis of ramipril (Hoe 498) [CAS: 87333-19-5][R0219], an ACE inhibitor.
References
- Synthesis of unnatural amino acids: (S,S,S)-2-azabicyclo[3.3.0]octane-3-carboxylic acid
- Synthesis of a highly active angiotensin converting enzyme inhibitor: 2-[N-[(S)-1-ethoxycarbonyl-3-phenylpropyl]-L-alanyl]-(1S,3S,5S)-2-azabicyclo[3.3.0]octane-3-carboxylic acid (Hoe 498)
- Asymmetric synthesis of (S,S,S)-2-aza-bicyclo[3.3.0]octane-3-carboxylic acid benzyl ester. Formal synthesis of ramipril
PubMed Literature
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