text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 87413-09-0 | Product Number: D2045

Dess-Martin Periodinane

Purity: >95.0%(T)
  • 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one
  • DMP
45,00 €
1   30  
98,00 €
10   ≥40 
245,00 €
5   ≥40 

*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).


This product may generate a little insoluble matter overtime while storing.
Since no effect the reaction, please filtering as needed before use.

Product Number D2045
Purity / Analysis Method >95.0%(T)
Molecular Formula / Molecular Weight C__1__3H__1__3IO__8 = 424.14 
Physical State (20 deg.C) Solid
Storage Temperature -20°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive,Moisture Sensitive,Heat Sensitive
CAS RN 87413-09-0
Reaxys Registry Number 4548207
PubChem Substance ID 87568496
Merck Index (14) 2933
MDL Number


Appearance White to Almost white powder to crystal
Purity(Iodometric Titration) min. 95.0 %
NMR confirm to structure
Properties (reference)
Melting Point 124 °C(dec.)
Solubility (soluble in) Acetone,Chloroform
Solubility (slightly sol. in) Ether
Pictogram Pictogram Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H341 : Suspected of causing genetic defects.
H272 : May intensify fire; oxidizer.
Precautionary Statements P220 : Keep away from clothing and other combustible materials.
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P201 : Obtain special instructions before use.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Related Laws:
Transport Information:
UN Number UN1479
Class 5.1
Packing Group III
HS Number 2934999090
TCI Practical Example: Mild Oxidation Using Dess-Martin Periodinane

Used Chemicals


To dichloromethane (10 mL) was added trans-2-phenyl-1-cyclohexanol (0.30 g,1.7 mmol) and DMP (0.72 g, 1.7 mmol) at room temperature. The reaction mixture was stirred overnight at room temperature, then diluted with diethyl ether and washed with saturated aqueous sodium bicarbonate, 10% aqueous sodium thiosulfate, water and brine. The organic layer was concentrated under reduced pressure. The resulting crude product was purified by column chromatography (hexane:ethyl acetate = 8:1 on silica gel) to give 1 as a white solid (0.22 g, 74% yield).

Experimenter’s Comments

The reaction mixtures were monitored by TLC (hexane:ethyl acetate = 4:1).

Analytical Data(2-Phenylcyclohexanone (1))

1H NMR (400 MHz, CDCl3); δ 7.37-7.31 (m, 2H), 7.30-7.22 (m, 1H), 7.17-7.12 (m, 2H), 3.62 (dd, 1H, J = 12.4, 6.9 Hz), 2.58-2.41 (m, 2H), 2.33-2.23 (m, 1H), 2.22-2.10 (m, 1H), 2.10-1.94 (m, 2H), 1.91-1.75 (m, 2H).

13C NMR (101 MHz, CDCl3); δ 210.5, 138.9, 128.6, 128.5, 127.0, 57.5, 42.3, 35.2, 27.9, 25.5.

Lead Reference

Dess-Martin Periodinane Reagent


PubMed Literature


Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.

The requested SDS is not available.

Please Contact Us for more information.

C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number is entered
Analytical Charts
Please enter Lot Number Incorrect Lot Number is entered

The requested analytical chart is not available. Sorry for the inconvenience.

Other Documents

Session Status
Your session will timeout in 10 minutes. You will be redirected to the HOME page after session timeout. Please click the button to continue session from the same page. minute. You will be redirected to the HOME page after session timeout. Please click the button to continue session from the same page.

Your session has timed out. You will be redirected to the HOME page.