Maximum quantity allowed is 999
Please select the quantity
CAS RN: 1155843-79-0 | Product Number: H1404
2-Hydroxy-2-azaadamantane
×
![]()
×
Purity: >98.0%(T)
Synonyms:
- AZADOL®
Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 200MG |
€67.00
|
1 | 17 |
|
| 1G |
€264.00
|
1 | 6 |
|
| 5G |
€1,033.00
|
4 | 5 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Note:
AZADOL® is a registered trademark of Nissan Chemical Industries, Ltd.
Specifications
| Appearance | White to Gray to Brown powder to crystal |
| Purity(GC) | min. 97.0 % |
| Purity(Nonaqueous Titration) | min. 98.0 % |
Properties (reference)
GHS
Related Laws:
Transport Information:
| HS Number | 2933399990 |
Application
AZADO Catalyzed One-Pot Oxidative Cleavage of Vicinal Diols to (Di)Carboxylic Acids
Typical Procedure (R1 = BzO(CH2)7-, R2 = H): To a solution of 9,10-dihydroxydecyl benzoate (30.0 mg, 0.102 mmol) in CH2Cl2 (0.26 mL) and H2O (0.26 mL) is added AZADOL (1.6 mg, 0.0102 mmol) and PhI(OAc)2 (164 mg, 0.510 mmol) at 0 °C. The mixture is allowed to warm to room temperature and stirred for 1 h. Then, 10% HCl is added to the mixture and the resultant solution is extracted with CH2Cl2. The combined organic layer is washed with brine, dried over MgSO4 and concentrated under reduced pressure. The crude product is purified by silica gel column chromatography (eluent: AcOEt/Hexane = 1/8 to only AcOEt) to give 9-(benzoyloxy)nonanoic acid (26.8 mg, 0.0963 mmol, 94%) as white solid.
References
- 1)M. Shibuya, T. Shibuta, H. Fukuda, Y. Iwabuchi, Org. Lett. 2012, 14, 5010.
- 2)A review on AZADO for oxidation of alcohols.
Application
Alcohol Oxidation Catalyst Showing Higher Activity than TEMPO
References
- 1)Y. Iwabuchi, Chem. Pharm. Bull. 2013, 61, 1197.
- 2)M. Shibuya, Y. Sasano, M. Tomizawa, T. Hamada, M. Kozawa, N. Nagahama, Y. Iwabuchi, Synthesis 2011, 3418.
- 3)Y. Iwabuchi, M. Shibuya, M. Tomizawa, Y. Osada, PCT Int. Appl. WO 2009145323, 2009.
- 4)M. Hayashi, M. Shibuya, Y. Iwabuchi, Org. Lett. 2012, 14, 154.
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Alcohol Oxidation Catalyst Showing Higher Activity than TEMPO[Research Articles] AZADO Catalyzed One-Pot Oxidative Cleavage of Vicinal Diols to (Di)Carboxylic Acids
Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number is entered
Analytical Charts
Please enter Lot Number
Incorrect Lot Number is entered
The requested analytical chart is not available. Sorry for the inconvenience.