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CAS RN: 1155843-79-0 | Product Number: H1404

2-Hydroxy-2-azaadamantane


Purity: >98.0%(T)
Synonyms:
  • AZADOL®
Documents:
200MG
67,00 €
Contact Us 6  
1G
264,00 €
3   25  
5G
1.033,00 €
4   25  

*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).


Note:

AZADOL® is a registered trademark of Nissan Chemical Industries, Ltd.

Product Number H1404
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__9H__1__5NO = 153.23 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
CAS RN 1155843-79-0
Reaxys Registry Number 21286916
PubChem Substance ID 172089100
Specifications
Appearance White to Gray to Brown powder to crystal
Purity(GC) min. 97.0 %
Purity(Nonaqueous Titration) min. 98.0 %
Properties (reference)
GHS
Related Laws:
Transport Information:
HS Number 2933399990
Application
AZADO Catalyzed One-Pot Oxidative Cleavage of Vicinal Diols to (Di)Carboxylic Acids

Typical Procedure (R1 = BzO(CH2)7-, R2 = H): To a solution of 9,10-dihydroxydecyl benzoate (30.0 mg, 0.102 mmol) in CH2Cl2 (0.26 mL) and H2O (0.26 mL) is added AZADOL (1.6 mg, 0.0102 mmol) and PhI(OAc)2 (164 mg, 0.510 mmol) at 0 °C. The mixture is allowed to warm to room temperature and stirred for 1 h. Then, 10% HCl is added to the mixture and the resultant solution is extracted with CH2Cl2. The combined organic layer is washed with brine, dried over MgSO4 and concentrated under reduced pressure. The crude product is purified by silica gel column chromatography (eluent: AcOEt/Hexane = 1/8 to only AcOEt) to give 9-(benzoyloxy)nonanoic acid (26.8 mg, 0.0963 mmol, 94%) as white solid.

References


Application
Alcohol Oxidation Catalyst Showing Higher Activity than TEMPO

References


PubMed Literature


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