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CAS RN: 15418-29-8 | Product Number: T2666

Tetrakis(acetonitrile)copper(I) Tetrafluoroborate


Purity: >98.0%(T)
Synonyms:
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Product Number T2666
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__8H__1__2BCuF__4N__4 = 314.56  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 15418-29-8
Reaxys Registry Number 4925687
PubChem Substance ID 87561637
MDL Number

MFCD09265110

Specifications
Appearance White to Almost white powder to crystal
Purity(Potassium permanganate method) min. 98.0 %
Properties (reference)
Melting Point 164 °C(dec.)
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
Precautionary Statements P260 : Do not breathe dust or mist.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws:
Transport Information:
UN Number UN1759
Class 8
Packing Group III
HS Number 2926907090
Application
DABSO as a SO2 Source Usable for Direct Sulfonylative-Suzuki Coupling of Aryl Boronic Acids

Reference


Application
Copper-Catalyzed Radical Cyclization of Aryl Amines

T2666

Typical Procedure (X = Cl, Y = O, n = 1, R1, R2 and R3 = H):
To a dried Schlenk-tube containing 2-(allyloxy)aniline (0.5 mmol, 74.6 mg, 1 eq.), tert-butyl nitrite (0.55 mmol, 56.7 mg, 1.1 eq.) in acetone (5.0 mL) at 0 °C, Cu(CH3CN)4BF4 (0.05 mmol, 15.7 mg) and conc. HCl aq (2.5 eq.) are added. The reaction mixture is warmed to room temperature and stirred for 3 h. After completion, most of the solvent is removed in vacuo and the residue is purified by flash chromatography on silica gel (eluent: pentane) to afford 3-(chloromethyl)-2,3-dihydrobenzofuran as a colorless oil (0.46 mmol, 77.6 mg, 92% yield).

References


PubMed Literature


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