text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 60804-75-3 | Product Number: T3208

Tris(1,10-phenanthroline)ruthenium(II) Bis(hexafluorophosphate)


Purity: >98.0%(HPLC)
Synonyms:
Documents:
200MG
€50.00
1   24  
1G
€175.00
2   12  

*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).


Product Number T3208
Purity / Analysis Method >98.0%(HPLC)
Molecular Formula / Molecular Weight C__3__6H__2__4F__1__2N__6P__2Ru = 931.63 
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
CAS RN 60804-75-3
Reaxys Registry Number 16803830
PubChem Substance ID 253660837
Specifications
Appearance Light yellow to Brown powder to crystal
Purity(HPLC) min. 98.0 area%
Elemental analysis(Nitrogen) 8.50 to 9.50 %
Properties (reference)
Maximum Absorption Wavelength 445(DMSO) nm
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
HS Number 2843909000
Application
TCI Practical Example: The Intermolecular [2+2] Cycloaddition Catalyzed by a Photoredox Catalyst

TCI Practical Example: The Intermolecular [2+2] Cycloaddition Catalyzed by a Photoredox Catalyst

Used Chemicals

Procedure

A 3-neck round bottom flask was charged with 1 (0.1 g, 0.5 mmol, 1 eq), 1,1-diphenylethylene (0.2 g, 1 mmol, 2 eq), Ru(phen)3(PF6)2 (0.009 g, 0.01 mmol, 2 mol%), degassed acetone (12.5 mL) at rt under N2. The mixture was placed at a distance of 2-3 cm from Blue LED lamp with a cooling fan. The reaction mixture was stirred at rt under visible light irradiation. After 19 h of irradiation, the solvent was removed in vacuo, giving crude as a blown oil (0.32 g). The crude was purified by silica gel column chromatography (hexane:ethyl acetate = 10:1, Rf = 0.57) to give compound 2 as a colorless sticky solid (0.12 g, y. 60%)

Experimenter’s Comments

  • Acetone was degassed with nitrogen for 30 min before use.
  • Irradiation of visible light was performed with Kessil A160WE Tuna Blue 40Wx2.
  • Temperature of the reaction mixture was maintained at rt by a cooling fan.
  • The reaction mixture was monitored by 1H NMR and TLC.

Analytical Data

Compound 2

1H NMR (400 MHz, CDCl3); δ 7.33−7.27 (m, 4H), 7.20−7.12 (m, 4H), 7.00−6.98 (m, 2H), 6.83−6.78 (m, 4H), 4.54 (d, J = 9.2 Hz, 1H), 4.28−4.01 (m, 3H), 3.49-3.36 (m, 1H), 2.66 (t, J = 10.5 Hz, 1H),1.20 (t, J = 7.3 Hz, 3H).

13C NMR (101 MHz, CDCl3); δ 193.4, 161.8 (d, JC‑F = 247.49 Hz), 161.3, 161.0, 150.0, 140.8, 133.8 (d, JC‑F = 2.9 Hz), 130.3 (d, JC‑F = 7.7 Hz), 128.5, 128.4, 128.0, 126.4, 126.1, 114.6 (d, JC‑F = 21.1 Hz), 62.5, 53.6, 52.9, 44.0, 33.7, 14.5.

19F NMR (376 MHz, CDCl3); δ -116.39 (s, 1F).

Lead Reference

Other Reference


PubMed Literature


Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.

The requested SDS is not available.

Please Contact Us for more information.

Specifications
C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number is entered
Analytical Charts
Please enter Lot Number Incorrect Lot Number is entered

The requested analytical chart is not available. Sorry for the inconvenience.

Other Documents