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CAS RN: 51479-73-3 | Product Number: A2186

Allyl 2,2,2-Trichloroacetimidate


Purity: >98.0%(GC)
Synonyms:
  • 2,2,2-Trichloroacetimidic Acid Allyl Ester
Documents:
5G
£63.00
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Product Number A2186
Purity / Analysis Method >98.0%(GC)
Molecular Formula / Molecular Weight C__5H__6Cl__3NO = 202.46  
Physical State (20 deg.C) Liquid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive,Heat Sensitive
CAS RN 51479-73-3
Reaxys Registry Number 1907084
PubChem Substance ID 125307218
MDL Number

MFCD00190710

Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 98.0 %
Properties (reference)
Boiling Point 74 °C/11 mmHg
Flash point 74 °C
Specific Gravity (20/20) 1.34
Refractive Index 1.49
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H315 : Causes skin irritation.
H318 : Causes serious eye damage.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws: / Compliance with laws, Regulations
Transport Information:
HS Number 2925290090
Application
Allylation Reagent

Typical Procedure:
A solution of allyl 2,2,2-trichloroacetimidate (2 mmol) in cyclohexane (2 mL) and subsequently BF3·Et2O (20 µL) are added to a stirred solution of the carboxylic acid (1 mmol) in CH2Cl2 (1 mL). After stirring at room temperature overnight the precipitated trichloroacetamide is removed by filtration. The filtrate is washed with 5% NaHCO3 aq., brine and then dried (Na2SO4). The solvent is evaporated under reduced pressure and the residue is purified by distillation or column chromatography using petroleum ether (40-60 °C) / EtOAc (9 : 1) as an eluent.

References


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