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CAS RN: 34671-83-5 | Product Number: B2496
2,2'-Bipyrimidyl
Purity: >95.0%(GC)
Synonyms:
- 2,2'-Bipyrimidine
- 2,2'-Dipyrimidyl
Product Documents:
Size | Unit Price | Belgium | Japan* | Quantity |
---|---|---|---|---|
200MG |
£24.00
|
1 | 29 |
|
1G |
£113.00
|
5 | ≥40 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Product Number | B2496 |
Purity / Analysis Method | >95.0%(GC) |
Molecular Formula / Molecular Weight | C__8H__6N__4 = 158.16 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
CAS RN | 34671-83-5 |
Reaxys Registry Number | 607396 |
PubChem Substance ID | 135727183 |
MDL Number | MFCD00014600 |
Specifications
Appearance | White to Green to Brown powder to crystal |
Purity(GC) | min. 95.0 % |
Properties (reference)
Melting Point | 113 °C |
Solubility (soluble in) | Methanol |
GHS
Pictogram | |
Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
EC Number | 252-137-2 |
Transport Information:
HS Number | 2933599590 |
Application
Heterodinuclear Metal Complex via Bridging Ligand
2,2'-Bipyrimidyl behaves as a metalloligand like 2,2'-bipyridyls and can be coordinately bonded to two kinds of metals. For example, Fukuzumi et al. have reported the synthesis of a heterodinuclear iridium-ruthenium complex (1) using 2,2'-bipyrimidyl. 1 acts as a catalyst for four-electron reduction of dissolved O2 with formic acid in water. Besides this, Irfanullah and Iftikhar have reported the synthesis of a europium-terbium complex (2) as a heterodilanthanide complex. The luminescence of Eu(III) is enhanced by intramolecular energy transfer from Tb(III) to Eu(III) in the complex.
References
- S. Fukuzumi, T. Kobayashi, T. Suenobu, J. Am. Chem. Soc. 2010, 132, 11866.
- M. Irfanullah, K. Iftikhar, Inorg. Chem. Commun. 2010, 13, 694.
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