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Published TCIMAIL newest issue No.199
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CAS RN: 61078-14-6 | Product Number: M2860
1-Methyl-2-(methylsulfonyl)benzimidazole
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Purity: >97.0%(GC)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
£94.00
|
1 | 15 |
|
|
| 5G |
£323.00
|
1 | 26 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
| Product Number | M2860 |
Purity / Analysis Method 
|
>97.0%(GC) |
| Molecular Formula / Molecular Weight | C__9H__1__0N__2O__2S = 210.25 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive,Heat Sensitive |
| Packaging and Container
|
1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 61078-14-6 |
| Reaxys Registry Number | 172457 |
| PubChem Substance ID | 354333689 |
Specifications
| Appearance | White to Light yellow to Light orange powder to crystal |
| Purity(GC) | min. 97.0 % |
| Melting point | 132.0 to 136.0 °C |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 134 °C |
| Maximum Absorption Wavelength | 278 nm (EtOH) |
GHS
Related Laws:
Transport Information:
| HS Number | 2933998090 |
Application
新しいJulia型メチレン化試薬
Experimental procedure: to a solution of 1 (0.076 g, 0.36 mmol) and p-methoxyacetophenone (0.045 g, 0.30 mmol) in DMF (1.5 mL) under argon is added tert-BuOK (0.101 g, 0.90 mmol) at room temperature. After stirring for 1 h, the reaction is quenched with an aqueous NH4Cl solution and the mixture is extracted with AcOEt (2 x 10 mL). The combined extracts are washed with H2O (3 x 10 mL), brine, dried (MgSO4), and concentrated. Column chromatography (silica gel; hexane : AcOEt = 10 : 1) provides 2-(4-methoxyphenyl)propene (0.041 g, 92%) as a colorless solid.
References
- Practical methylenation reaction for aldehydes and ketones using new Julia-type reagents
PubMed Literature
Product Articles
[TCIMAIL No.170] A New Julia-Type Reagent for Methylenation Reactions[Product Highlights] A New Julia-Type Reagent for Methylenation Reactions
Product Documents (Note: Some products will not have analytical charts available.)
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