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CAS RN: 100-63-0 | Product Number: P0183

Phenylhydrazine


Purity: >98.0%(GC)(T)
Synonyms:
Documents:
25G
£14.00
6   ≥20 
100G
£20.00
3   ≥20 
500G
£63.00
2   ≥20 

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Product Number P0183
Purity / Analysis Method >98.0%(GC)(T)
Molecular Formula / Molecular Weight C__6H__8N__2 = 108.14  
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive
CAS RN 100-63-0
Reaxys Registry Number 606080
PubChem Substance ID 87574432
SDBS (AIST Spectral DB) 561
Merck Index (14) 7293
MDL Number

MFCD00007573

Specifications
Appearance White to Orange to Green powder to lump
Purity(GC) min. 98.0 %
Purity( Potassium iodate Method) min. 98.0 %
Properties (reference)
Melting Point 19 °C
Flash point 88 °C
Specific Gravity (20/20) 1.10
Refractive Index 1.61
Solubility in water Soluble
Degree of solubility in water 837 grm/l   24 °C
Solubility (miscible with) Ether,Alcohol,Benzene,Chloroform
Solubility (very soluble in) Acetone
GHS
Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H310 : Fatal in contact with skin.
H301 + H331 : Toxic if swallowed or if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H372 : Causes damage to organs through prolonged or repeated exposure.
H370 : Causes damage to organs.
H317 : May cause an allergic skin reaction.
H341 : Suspected of causing genetic defects.
H350 : May cause cancer.
H400 : Very toxic to aquatic life.
Precautionary Statements P273 : Avoid release to the environment.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P262 : Do not get in eyes, on skin, or on clothing.
P201 : Obtain special instructions before use.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P391 : Collect spillage.
P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor.
P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.
P302 + P352 + P310 : IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/doctor.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
Related Laws:
EC Number 202-873-5
RTECS# MV8925000
Transport Information:
UN Number UN2572
Class 6.1
Packing Group II
HS Number 2928009090
Application
Reagent for anemia model

References


Application
Direct Radical Arylation of Unactivated Arenes Using Phenyl Hydrazine

P0183

Typical Procedure: KOt-Bu (0.101 g, 0.9 mmol, 3.0 eq.), aryl iodide (0.3 mmol, 1.0 eq.) and benzene (2.8 mL) are added into a flame dried Schlenk tube under argon atmosphere. Then a 0.15 M solution of phenylhydrazine (0.2 mL, 0.03 mmol, 0.1 eq.) in benzene is added to this heterogeneous reaction mixture over 6 h using a syringe pump at 100 °C. After complete addition, the reaction mixture is stirred for an additional 24 h at 100 °C. After that it is cooled to room temperature, quenched with water (4 mL) and subsequently extracted with ethyl acetate (3 x 20 mL). The combined organic phase is washed with brine (5 mL), dried over anhydrous Na2SO4, filtered and concentrated under vacuum. The crude product is purified by flash column chromatography using pentane or a 95:05 mixture of pentane/ethyl acetate as an eluent.

References


PubMed Literature


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