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CAS RN: 64536-78-3 | Product Number: C2824
(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate
Purity:
Synonyms:
- Crabtree's Catalyst
Product Documents:
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| Product Number | C2824 |
| Molecular Formula / Molecular Weight | C__3__1H__5__0F__6IrNP__2 = 804.90 |
| Physical State (20 deg.C) | Solid |
Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Moisture Sensitive |
Packaging and Container
|
100MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 64536-78-3 |
| Reaxys Registry Number | 16178060 |
| PubChem Substance ID | 253659537 |
| MDL Number | MFCD00075097 |
Specifications
| Appearance | Light yellow to Brown powder to crystal |
| Elemental analysis(Nitrogen) | 1.50 to 1.80 % |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 175 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| H.S.code* | 2843.90-000 |
Application
Crabtree's Catalyst: a Homogeneous Catalyst for Hydrogenation

References
- 1)Total Synthesis of (+)-Azaspiracid-1. An Exhibition of the Intricacies of Complex Molecule Synthesis
- 2)Directing Effects in Homogeneous Hydrogenation with [Ir(cod)(PCy3)(py)]PF6
PubMed Literature
Documents
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