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CAS RN: 104439-77-2 | Product Number: H1322

1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)


Purity:
Synonyms:
  • Shvo's Catalyst
Documents:
100MG
$94.00
8   15  

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* The storage conditions are subject to change without notice.


Product Number H1322
Molecular Formula / Molecular Weight C__6__2H__4__2O__6Ru__2 = 1,085.15 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Moisture Sensitive
Packaging and Container 100MG-Glass Bottle with Plastic Insert (View image)
CAS RN 104439-77-2
PubChem Substance ID 125308084
Merck Index (14) 8483
MDL Number

MFCD03840556

Specifications
Appearance Light yellow to Brown powder to crystal
Elemental analysis(Carbon) 67.0 to 71.0 %
Properties (reference)
Melting Point 227 °C
GHS
Related Laws:
Transport Information:
H.S.code* 2843.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Reviews

References


Application
Anti-Markovnikov Hydration of Vinylarenes via Triple Relay Catalysis

Typical procedure (R = H): PdCl2(CH3CN)2 (10.4 mg), Shvo’s catalyst (43.6 mg), CuCl2 (10.8 mg) and 1,4-benzoquinone (43.2 mg) are weighed into a 20 mL vial under a nitrogen atmosphere, followed by the addition of i-PrOH (2 mL) and t-BuOH (4 mL). Styrene (41.7 mg) is added to the mixture followed by addition of H2O (8.1 µL). After the resulting mixture is stirred at 85 °C for 6 h, it is diluted with pentane (6 mL) and filtered through a plug of silica gel followed by flushing with ethyl acetate (6 mL). The solvent is removed under vacuum, and the residue is purified by silica gel flash chromatography to give 2-phenylethyl alcohol (41 mg, 87 % yield).

References


Application
Synthesis of Aromatic Amines under Catalytic Transfer Hydrogenation Conditions

Typical procedure (entry 1): In a pressure tube under an argon atmosphere, the Shvo’s catalyst (22 mg), p-toluidine (429 mg), and hexylamine (202 mg) are dissolved in tert-amyl alcohol (0.5 ml). The pressure tube is fitted with a polytetrafluoroethylene cap and heated at 150 °C for 24 h in an oil bath. The solvent is removed in vacuo, and the crude product is purified by column chromatography (eluent: pentane/ethyl acetate) to give N-hexyl-4-methylaniline as colorless crystals (374 mg, 98 %).

References


PubMed Literature


Documents (Note: Some products will not have analytical charts available.)
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