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CAS RN: 60804-75-3 | Product Number: T3208

Tris(1,10-phenanthroline)ruthenium(II) Bis(hexafluorophosphate)


Purity: >98.0%(HPLC)
Synonyms:
Documents:
200MG
$69.00
2   25  
1G
$238.00
5   3  

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* The storage conditions are subject to change without notice.


Product Number T3208
Purity / Analysis Method >98.0%(HPLC)
Molecular Formula / Molecular Weight C__3__6H__2__4F__1__2N__6P__2Ru = 931.63 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image),  200MG-Glass Bottle with Plastic Insert (View image)
CAS RN 60804-75-3
Reaxys Registry Number 16803830
PubChem Substance ID 253660837
Specifications
Appearance Light yellow to Brown powder to crystal
Purity(HPLC) min. 98.0 area%
Elemental analysis(Nitrogen) 8.50 to 9.50 %
Properties (reference)
Maximum Absorption Wavelength 445(DMSO) nm
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
H.S.code* 2843.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
TCI Practical Example: The Intermolecular [2+2] Cycloaddition Catalyzed by a Photoredox Catalyst

TCI Practical Example: The Intermolecular [2+2] Cycloaddition Catalyzed by a Photoredox Catalyst

Used Chemicals

Procedure

A 3-neck round bottom flask was charged with 1 (0.1 g, 0.5 mmol, 1 eq), 1,1-diphenylethylene (0.2 g, 1 mmol, 2 eq), Ru(phen)3(PF6)2 (0.009 g, 0.01 mmol, 2 mol%), degassed acetone (12.5 mL) at rt under N2. The mixture was placed at a distance of 2-3 cm from Blue LED lamp with a cooling fan. The reaction mixture was stirred at rt under visible light irradiation. After 19 h of irradiation, the solvent was removed in vacuo, giving crude as a blown oil (0.32 g). The crude was purified by silica gel column chromatography (hexane:ethyl acetate = 10:1, Rf = 0.57) to give compound 2 as a colorless sticky solid (0.12 g, y. 60%)

Experimenter’s Comments

  • Acetone was degassed with nitrogen for 30 min before use.
  • Irradiation of visible light was performed with Kessil A160WE Tuna Blue 40Wx2.
  • Temperature of the reaction mixture was maintained at rt by a cooling fan.
  • The reaction mixture was monitored by 1H NMR and TLC.

Analytical Data

Compound 2

1H NMR (400 MHz, CDCl3); δ 7.33−7.27 (m, 4H), 7.20−7.12 (m, 4H), 7.00−6.98 (m, 2H), 6.83−6.78 (m, 4H), 4.54 (d, J = 9.2 Hz, 1H), 4.28−4.01 (m, 3H), 3.49-3.36 (m, 1H), 2.66 (t, J = 10.5 Hz, 1H),1.20 (t, J = 7.3 Hz, 3H).

13C NMR (101 MHz, CDCl3); δ 193.4, 161.8 (d, JC‑F = 247.49 Hz), 161.3, 161.0, 150.0, 140.8, 133.8 (d, JC‑F = 2.9 Hz), 130.3 (d, JC‑F = 7.7 Hz), 128.5, 128.4, 128.0, 126.4, 126.1, 114.6 (d, JC‑F = 21.1 Hz), 62.5, 53.6, 52.9, 44.0, 33.7, 14.5.

19F NMR (376 MHz, CDCl3); δ -116.39 (s, 1F).

Lead Reference

Other Reference


PubMed Literature


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