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CAS RN: 35138-22-8 | Product Number: B3961

Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate


Purity:
Synonyms:
Documents:
100MG
€50.00
2   ≥20 
1G
€197.00
3   ≥20 

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Product Number B3961
Molecular Formula / Molecular Weight C__1__6H__2__4BF__4Rh = 406.08  
Physical State (20 deg.C) Solid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Hygroscopic,Heat Sensitive
CAS RN 35138-22-8
Reaxys Registry Number 14342367
PubChem Substance ID 172088994
MDL Number

MFCD00075045

Specifications
Appearance Orange to Amber to Dark red powder to crystal
Elemental analysis(Carbon) 44.50 to 49.00 %
Properties (reference)
Melting Point 184 °C(dec.)
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
Precautionary Statements P260 : Do not breathe dust or mist.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws: / Compliance with laws, Regulations
Enzyme Commission 460-220-1
Transport Information:
UN Number UN1759
Class 8
Packing Group III
HS Number 2843909000
Application
Enantioselective Synthesis of Bicyclo Compounds Catalyzed by Rhodium and Benzoic Acid



References

K. Masutomi, K. Noguchi, K. Tanaka, J. Am. Chem. Soc. 2014, 136, 7627.


Application
C-H Activation Reaction for Aryl Ketones

References

Cationic Rh(I)/Modified-BINAP-Catalyzed Reactions of Carbonyl Compounds with 1,6-Diynes Leading to Dienones and Ortho-Functionalized Aryl Ketones

K. Tanaka, Y. Otake, A. Wada, K. Noguchi, M. Hirano, Org. Lett. 2007, 9, 2203.


Application
Enantioselective Isomerization of Allylic Alcohols
References

Enantioselective Isomerization of Allylic Alcohols Catalyzed by a Rhodium/Phosphaferrocene Complex

K. Tanaka, S. Qiao, M. Tobisu, M. M.-C. Lo, G. C. Fu, J. Am. Chem. Soc. 2000, 122, 9870.

A Versatile New Catalyst for the Enantioselective Isomerization of Allylic Alcohols to Aldehydes: Scope and Mechanistic Studies

K. Tanaka, G. C. Fu, J. Org. Chem. 2001, 66, 8177.


PubMed Literature


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