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CAS RN: 35138-22-8 | Product Number: B3961

Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate

1   15  
1   ≥20 

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Product Number B3961
Molecular Formula / Molecular Weight C__1__6H__2__4BF__4Rh = 406.08  
Physical State (20 deg.C) Solid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Hygroscopic,Heat Sensitive
CAS RN 35138-22-8
Reaxys Registry Number 14342367
PubChem Substance ID 172088994
MDL Number


Appearance Orange to Amber to Dark red powder to crystal
Elemental analysis(Carbon) 44.50 to 49.00 %
Properties (reference)
Melting Point 184 °C(dec.)
Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
Precautionary Statements P260 : Do not breathe dust or mist.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws:
EC Number 460-220-1
Transport Information:
UN Number UN1759
Class 8
Packing Group III
HS Number 2843909000
Enantioselective Synthesis of Bicyclo Compounds Catalyzed by Rhodium and Benzoic Acid

K. Masutomi, K. Noguchi, K. Tanaka, J. Am. Chem. Soc. 2014, 136, 7627.

C-H Activation Reaction for Aryl Ketones

Cationic Rh(I)/Modified-BINAP-Catalyzed Reactions of Carbonyl Compounds with 1,6-Diynes Leading to Dienones and Ortho-Functionalized Aryl Ketones

K. Tanaka, Y. Otake, A. Wada, K. Noguchi, M. Hirano, Org. Lett. 2007, 9, 2203.

Enantioselective Isomerization of Allylic Alcohols

Enantioselective Isomerization of Allylic Alcohols Catalyzed by a Rhodium/Phosphaferrocene Complex

K. Tanaka, S. Qiao, M. Tobisu, M. M.-C. Lo, G. C. Fu, J. Am. Chem. Soc. 2000, 122, 9870.

A Versatile New Catalyst for the Enantioselective Isomerization of Allylic Alcohols to Aldehydes: Scope and Mechanistic Studies

K. Tanaka, G. C. Fu, J. Org. Chem. 2001, 66, 8177.

PubMed Literature

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