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CAS RN: 2373-51-5 | Product Number: C0608

Chloromethyl Methyl Sulfide


Purity: >97.0%(GC)
Synonyms:
  • Chlorodimethyl Sulfide
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Product Number C0608
Purity / Analysis Method >97.0%(GC)
Molecular Formula / Molecular Weight C__2H__5ClS = 96.57  
Physical State (20 deg.C) Liquid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Heat Sensitive
CAS RN 2373-51-5
Reaxys Registry Number 1730851
PubChem Substance ID 87565704
SDBS (AIST Spectral DB) 4278
MDL Number

MFCD00000923

Specifications
Appearance Colorless to Light yellow to Light orange clear liquid
Purity(GC) min. 97.0 %
Properties (reference)
Boiling Point 106 °C
Flash point 17 °C
Specific Gravity (20/20) 1.17
Refractive Index 1.50
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H225 : Highly flammable liquid and vapour.
Precautionary Statements P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 : Keep container tightly closed.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
Related Laws: / Compliance with laws, Regulations
Enzyme Commission 219-148-4
RTECS# WQ3700000
Transport Information:
UN Number UN1993
Class 3
Packing Group II
HS Number 2930909899
Application
MTM(Methylthiomethyl) Protection of Alcohols using Chlorodimethyl Sulfide and Sodium Iodide

References

Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols

P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


Application
Protection of Hydroxy Groups
References

Protection of primary hydroxyl groups as methylthiomethyl ethers

E. J. Corey, M. G. Bock, Tetrahedron Lett. 1975, 16, 3269.

A mild and convenient method for the preparation of methylthiomethyl ethers: protection of hydroxyl groups

K. Suzuki, J. Inanaga, M. Yamaguchi, Chem. Lett. 1979, 8, 1277.


PubMed Literature


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