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CAS RN: 64536-78-3 | Product Number: C2824

(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate


Purity:
Synonyms:
  • Crabtree's Catalyst
Documents:
100MG
€140.00
3   ≥20 

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Product Number C2824
Molecular Formula / Molecular Weight C__3__1H__5__0F__6IrNP__2 = 804.9  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Moisture Sensitive
CAS RN 64536-78-3
Reaxys Registry Number 16178060
PubChem Substance ID 253659537
MDL Number

MFCD00075097

Specifications
Appearance Light yellow to Brown powder to crystal
Elemental analysis(Nitrogen) 1.50 to 1.80 %
Properties (reference)
Melting Point 175 °C(dec.)
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws: / Compliance with laws, Regulations
Transport Information:
HS Number 2843909000
Application
Crabtree's Catalyst: a Homogeneous Catalyst for Hydrogenation

References

1)Total Synthesis of (+)-Azaspiracid-1. An Exhibition of the Intricacies of Complex Molecule Synthesis

D. A. Evans, L. Kværnø, T. B. Dunn, A. Beauchemin, B. Raymer, J. A. Mulder, E. J. Olhava, M. Juhl, K. Kagechika, D. A. Favor, J. Am. Chem. Soc. 2008, 130, 16295.

2)Directing Effects in Homogeneous Hydrogenation with [Ir(cod)(PCy3)(py)]PF6

R. H. Crabtree, M. W. Davis, J. Org. Chem. 1986, 51, 2655.


PubMed Literature


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