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Published TCIMAIL newest issue No.199
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CAS RN: 1621182-04-4 | Product Number: C3327
Chloro[(1,2,3,4,5,6-η)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-κS][triisopropylphosphine-κP]ruthenium(II)
![Chemical Structure of Chloro[(1,2,3,4,5,6-eta)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-kappaS][triisopropylphosphine-kappaP]ruthenium(II)](/medias/C3327.jpg?context=bWFzdGVyfHJvb3R8NTk3Njh8aW1hZ2UvanBlZ3xhR015TDJoa1lpODRPVEl3T0RJME1ESXhNREl5TDBNek16STNMbXB3Wnd8MWNjOTk0MjFmODM3M2IzM2M0ODNiMWYxNzNmZTgwZWQxNmJlOGZhMDE5MmQxYmQ2NTU3MTE2N2NiNzU2OThlNQ "Chloro[(1,2,3,4,5,6-eta)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-kappaS][triisopropylphosphine-kappaP]ruthenium(II)")
![Thumbnail of Chloro[(1,2,3,4,5,6-eta)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-kappaS][triisopropylphosphine-kappaP]ruthenium(II)](/medias/C3327.jpg?context=bWFzdGVyfHJvb3R8MTYzNTB8aW1hZ2UvanBlZ3xhRFExTDJobVl5ODRPVE0wTWpRd01qSXpNall5TDBNek16STNMbXB3Wnd8MmEzYWEwMWE5MmFmZjI2M2VhMWYzNGU3Mzc5ZThmMzY0NmU1MTRjOWNkZWRkYjJjY2I3ZmI0YTdiNzg4MDUxYQ)
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![Chloro[(1,2,3,4,5,6-η)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-κS][triisopropylphosphine-κP]ruthenium(II)](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Chloro[(1,2,3,4,5,6-η)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-κS][triisopropylphosphine-κP]ruthenium(II)")
Purity:
Synonyms:
- [(DmpSR')RuCl(P-(i-Pr)3)]
Product Documents:
| Size | Unit Price | Belgium | Japan* |
|---|---|---|---|
| 100MG |
€219.00
|
3 | 34 |
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | C3327 |
| Molecular Formula / Molecular Weight | C__3__3H__4__6ClPRuS = 642.28 |
| Physical State (20 deg.C) | Solid |
Storage Temperature 
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 1621182-04-4 |
| PubChem Substance ID | 354334200 |
Specifications
| Appearance | Light yellow to Yellow to Orange powder to crystal |
| Elemental analysis(Carbon) | 59.00 to 64.00 % |
| Elemental analysis(Hydrogen) | 6.80 to 7.50 % |
| NMR | confirm to structure |
Properties (reference)
GHS
Related Laws:
Transport Information:
| HS Number | 2843909000 |
Application
Ruthenium Catalyst for Base-Free Synthesis of N-Silyl Enamines
References
- Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative Si-NCoupling
- Cooperative Catalytic Activation of Si-H Bonds by a Polar Ru-S Bond: Regioselective Low-Temperature C-H Silylation of Indoles under Neutral Conditions by a Friedel-Crafts Mechanism
PubMed Literature
Documents
Product Articles
[Product Highlights] Ruthenium Catalyst for Base-Free Synthesis of N-Silyl EnaminesProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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