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Published TCIMAIL newest issue No.201
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CAS RN: 13292-87-0 | Product Number: D1843
Dimethyl Sulfide Borane
×
Purity: >90.0%(T)
Synonyms:
- Borane - Dimethyl Sulfide Complex
- BMS
- Methyl Sulfide Borane
Product Documents:
| Size | Unit Price | Belgium | Japan* |
Shipping Information
|
|---|---|---|---|---|
| 25ML |
32,00 €
|
15 | 11 | |
| 100ML |
99,00 €
|
7 | 2 |
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
25mL and 100mL bottle of this product are attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| Product Number | D1843 |
Purity / Analysis Method 
|
>90.0%(T) |
| Molecular Formula / Molecular Weight | C__2H__6S·BH__3 = 75.96 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Moisture Sensitive,Heat Sensitive |
| Packaging and Container
|
100ML-DualSeal Bottle (View image), 25ML-DualSeal Bottle (View image) |
| CAS RN | 13292-87-0 |
| Reaxys Registry Number | 3663489 |
| PubChem Substance ID | 87568309 |
| MDL Number | MFCD00013189 |
Specifications
| Appearance | Colorless to Light yellow clear liquid |
| Purity(Neutralization titration) | min. 90.0 % |
| NMR | confirm to structure |
Properties (reference)
| Flash point | 18 °C |
| Specific Gravity (20/20) | 0.80 |
| Refractive Index | 1.46 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H318 : Causes serious eye damage. H225 : Highly flammable liquid and vapour. H260 : In contact with water releases flammable gases which may ignite spontaneously. |
| Precautionary Statements | P231 + P232 : Handle and store contents under inert gas. Protect from moisture. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P302 + P335 + P334 : IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 236-313-6 |
| RTECS# | PV5080000 |
Transport Information:
| UN Number | UN3399 |
| Class | 4.3 / 3 |
| Packing Group | I |
| HS Number | 2930909599 |
Application
A Stereoselective Hydroamination Transform To Access Polysubstituted Indolizidines
Reference
Application
Hydroboration
References
- S. Saito, T. Hasegawa, M. Inaba, R. Nishida, T. Fujii, S. Nomizu, T. Moriwake, Chem. Lett. 1984, 1389.
- L. M. Braun, R. A. Braun, H. R. Crissman, M. Opperman, R. M. Adams, J. Org. Chem. 1971, 36, 2388.
- C. F. Lane, J. Org. Chem. 1974, 39, 1437.
- R. O. Hutchins, F. Cistone, Org. Prep. Proced. Int. 1981, 13, 225.
- C. F. Lane, J. J. Daniels, Org. Synth. Coll. Vol. 1988, 6, 719.
- H. C. Brown, J. V. N. Vara Prasad, S-H. Zee, J. Org. Chem. 1986, 51, 439.
PubMed Literature
Please visit the Pubchem page at this link.
Product Articles
[Research Articles] A Stereoselective Hydroamination Transform To Access Polysubstituted IndolizidinesProduct Documents (Note: Some products will not have analytical charts available.)
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