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Published TCIMAIL newest issue No.199
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CAS RN: 674783-97-2 | Product Number: M1774
9-Mesityl-10-methylacridinium Perchlorate
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Purity: >98.0%(HPLC)
Synonyms:
- 10-Methyl-9-(2,4,6-trimethylphenyl)acridinium Perchlorate
Product Documents:
| Size | Unit Price | Belgium | Japan* |
|---|---|---|---|
| 1G |
€99.00
|
10 | ≥100 |
| 5G |
€320.00
|
1 | ≥60 |
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | M1774 |
Purity / Analysis Method 
|
>98.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__2__3H__2__2ClNO__4 = 411.88 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container
|
1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 674783-97-2 |
| Reaxys Registry Number | 9678980 |
| PubChem Substance ID | 87559030 |
Specifications
| Appearance | Light yellow to Amber to Dark green powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Purity(with Total Nitrogen) | min. 97.0 % |
Properties (reference)
| Solubility (soluble in) | Acetone |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H272 : May intensify fire; oxidizer. |
| Precautionary Statements | P220 : Keep away from clothing and other combustible materials. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. |
Related Laws:
Transport Information:
| UN Number | UN1479 |
| Class | 5.1 |
| Packing Group | III |
| HS Number | 2933998090 |
Application
Oxidant-Free Arene-Azole Cross-Coupling via [Acr+-Mes][ClO4-]
References
- Photo-induced oxidant-free oxidative C–H/N–H cross-coupling between arenes and azoles
Application
A Photocatalyst in Material Science and Synthetic Organic Chemistry
9-Mesityl-10-methylacridinium perchlorate is used as a photocatalyst for photoinduced electron transfer (PET) reactions in material science, and for photoredox catalytic organic reactions in synthetic organic chemistry.
References
- 9-Mesityl-10-methylacridinium: An Efficient Type II and Electron-Transfer Photooxygenation Catalyst
- Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System
- Organic synthetic transformations using organic dyes as photoredox catalysts (a review)
- Long-Lived Charge Separation and Applications in Artificial Photosynthesis (a review)
- The direct anti-Markovnikov addition of mineral acids to styrenes
Application
Selective Oxygenation using Effective Electron-Transfer Photocatalysts
References
- S. Fukuzumi, H. Kotani, K. Ohkubo, S. Ogo, N. V. Tkachenko, H. Lemmetyinen, J. Am. Chem. Soc. 2004, 126, 1600.
- H. Kotani, K. Ohkubo, S. Fukuzumi, J. Am. Chem. Soc. 2004, 126, 15999.
PubMed Literature
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