CAS RN: 60871-84-3 | Product Number: N0861
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|Purity / Analysis Method||>96.0%(T)|
|Molecular Formula / Molecular Weight||C__2F__6NiO__6S__2 = 356.82|
|Physical State (20 deg.C)||Solid|
|Store Under Inert Gas||Store under inert gas|
|Condition to Avoid||Moisture Sensitive|
|Reaxys Registry Number||10590495|
|PubChem Substance ID||125307294|
|Appearance||Light yellow to Yellow to Green powder to crystal|
|Purity(Chelometric Titration)||min. 96.0 %|
|Hazard Statements||H314 : Causes severe skin burns and eye damage.
H372 : Causes damage to organs through prolonged or repeated exposure.
H317 : May cause an allergic skin reaction.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H350 : May cause cancer.
|Precautionary Statements||P260 : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P201 : Obtain special instructions before use.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P308 + P313 : IF exposed or concerned: Get medical advice/ attention.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
In an oven-dried 5 mL screw-capped vial in a glovebox, 2-methyl-N-(8-quinolinyl)benzamide (79 mg, 0.3 mmol), iodobenzene (122 mg, 0.6 mmol), Ni(OTf)2 (5 mg, 0.015 mmol), NaHCO3 (50 mg, 0.6 mmol), and toluene (1 mL) are added. The mixture is stirred for 20 h at 160 °C followed by cooling. The mixture is filtered through a Celite pad and concentrated in vacuo. The residue is purified by column chromatography on silica gel (hexane : EtOAc = 10 : 1) to afford the desired arylated product (97 mg, Y. 94%) as a colorless oil.
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