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CAS RN: 60871-84-3 | Product Number: N0861

Nickel(II) Trifluoromethanesulfonate


Purity: >96.0%(T)
Synonyms:
  • Trifluoromethanesulfonic Acid Nickel(II) Salt
  • Nickel(II) Triflate
Documents:
1G
€41.00
2   ≥20 
5G
€149.00
5   ≥20 

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Product Number N0861
Purity / Analysis Method >96.0%(T)
Molecular Formula / Molecular Weight C__2F__6NiO__6S__2 = 356.82  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 60871-84-3
Reaxys Registry Number 10590495
PubChem Substance ID 125307294
MDL Number

MFCD00673740

Specifications
Appearance Light yellow to Yellow to Green powder to crystal
Purity(Chelometric Titration) min. 96.0 %
Properties (reference)
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
H372 : Causes damage to organs through prolonged or repeated exposure.
H317 : May cause an allergic skin reaction.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H350 : May cause cancer.
Precautionary Statements P260 : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P201 : Obtain special instructions before use.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P308 + P313 : IF exposed or concerned: Get medical advice/ attention.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws: / Compliance with laws, Regulations
Transport Information:
UN Number UN1759
Class 8
Packing Group III
HS Number 2904909590
Application
8-アミノキノリン部位を持つ芳香族アミドのC―H結合直接アリール化反応

N0861

Typical Procedure (Entry 1):
In an oven-dried 5 mL screw-capped vial in a glovebox, 2-methyl-N-(8-quinolinyl)benzamide (79 mg, 0.3 mmol), iodobenzene (122 mg, 0.6 mmol), Ni(OTf)2 (5 mg, 0.015 mmol), NaHCO3 (50 mg, 0.6 mmol), and toluene (1 mL) are added. The mixture is stirred for 20 h at 160 °C followed by cooling. The mixture is filtered through a Celite pad and concentrated in vacuo. The residue is purified by column chromatography on silica gel (hexane : EtOAc = 10 : 1) to afford the desired arylated product (97 mg, Y. 94%) as a colorless oil.

References


PubMed Literature


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