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CAS RN: 12354-85-7 | Product Number: P1788
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
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Purity: >96.0%(T)
Synonyms:
- Dichloro(pentamethylcyclopentadienyl)rhodium(III) Dimer
- [Cp*RhCl2]2
Product Documents:
| Size | Unit Price | Belgium | Japan* |
Shipping Information
|
|---|---|---|---|---|
| 200MG |
€112.00
|
5 | 8 | |
| 1G |
€422.00
|
7 | ≥100 |
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
| Product Number | P1788 |
Purity / Analysis Method 
|
>96.0%(T) |
| Molecular Formula / Molecular Weight | C__2__0H__3__0Cl__4Rh__2 = 618.07 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container
|
1G-Glass Bottle with Plastic Insert (View image), 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 12354-85-7 |
| PubChem Substance ID | 87560640 |
| MDL Number | MFCD00061552 |
Specifications
| Appearance | Light yellow to Brown powder to crystal |
| Purity(Argentometric Titration) | min. 96.0 % |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P261 : Avoid breathing dust. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
Related Laws:
Transport Information:
| HS Number | 2843909000 |
Application
Cp*-Rh catalyzed oxidative Heck reaction
References
- The Rhodium-catalyzed Selective Oxidative Heck Reaction of Amides with Allylic Esters
Application
Cp*-Rh catalyzed Direct Ar-H Sulfonamidation and Amination Reactions
References
- Rhodium(III)-catalyzed Direct C-7 Sulfonamidation and Amination of Indolines with Arylsulfonamides and Trifluoroacetamide
Application
Rhodium-catalyzed Annulation of N-Benzoylsulfonamide with Isocyanide through C―H Activation
Typical Procedure:
N-Benzoyl-4-methylbenzenesulfonamide (27.5 mg, 0.1 mmol), [RhCl2Cp*]2 (1.2 mg, 0.002 mmol) and Cu(OAc)2·H2O (40.0 mg, 0.2 mmol) are loaded in a dry vial which is subjected to evacuation/flushing with dry argon three times. A solution of 2,6-dimethylphenyl isocyanide (19.6 mg, 0.15 mmol) in anhydrous dichloroethane (0.8 mL) is syringed into the mixture that is then stirred at 130 °C for 20 h or until the starting material has been consumed as determined by TLC. Upon cooling to room temperature, all volatiles are evaporated and the residue is purified by preparative TLC (ethyl acetate : hexane = 1 : 2) to give the corresponding 3-(imino)isoindolinone derivative (Y. 70%, E/Z = 3 : 1). Z and E isomers are further separated by preparative TLC (methylene chloride : hexane = 10 : 1).
N-Benzoyl-4-methylbenzenesulfonamide (27.5 mg, 0.1 mmol), [RhCl2Cp*]2 (1.2 mg, 0.002 mmol) and Cu(OAc)2·H2O (40.0 mg, 0.2 mmol) are loaded in a dry vial which is subjected to evacuation/flushing with dry argon three times. A solution of 2,6-dimethylphenyl isocyanide (19.6 mg, 0.15 mmol) in anhydrous dichloroethane (0.8 mL) is syringed into the mixture that is then stirred at 130 °C for 20 h or until the starting material has been consumed as determined by TLC. Upon cooling to room temperature, all volatiles are evaporated and the residue is purified by preparative TLC (ethyl acetate : hexane = 1 : 2) to give the corresponding 3-(imino)isoindolinone derivative (Y. 70%, E/Z = 3 : 1). Z and E isomers are further separated by preparative TLC (methylene chloride : hexane = 10 : 1).
References
PubMed Literature
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