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CAS RN: 12354-85-7 | Product Number: P1788

(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer


Purity: >96.0%(T)
Synonyms:
  • Dichloro(pentamethylcyclopentadienyl)rhodium(III) Dimer
Documents:
200MG
€105.00
9   ≥20 
1G
€393.00
5   ≥20 

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Product Number P1788
Purity / Analysis Method >96.0%(T)
Molecular Formula / Molecular Weight C__2__0H__3__0Cl__4Rh__2 = 618.07  
Physical State (20 deg.C) Solid
CAS RN 12354-85-7
PubChem Substance ID 87560640
MDL Number

MFCD00061552

Specifications
Appearance Light yellow to Amber to Dark green powder to crystal
Purity(Argentmetric Titration) min. 96.0 %
Properties (reference)
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P261 : Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
Related Laws: / Compliance with laws, Regulations
Transport Information:
HS Number 2843909000
Application
Rhodium-catalyzed Annulation of N-Benzoylsulfonamide with Isocyanide through C―H Activation

Typical Procedure:
N-Benzoyl-4-methylbenzenesulfonamide (27.5 mg, 0.1 mmol), [RhCl2Cp*]2 (1.2 mg, 0.002 mmol) and Cu(OAc)2·H2O (40.0 mg, 0.2 mmol) are loaded in a dry vial which is subjected to evacuation/flushing with dry argon three times. A solution of 2,6-dimethylphenyl isocyanide (19.6 mg, 0.15 mmol) in anhydrous dichloroethane (0.8 mL) is syringed into the mixture that is then stirred at 130 °C for 20 h or until the starting material has been consumed as determined by TLC. Upon cooling to room temperature, all volatiles are evaporated and the residue is purified by preparative TLC (ethyl acetate : hexane = 1 : 2) to give the corresponding 3-(imino)isoindolinone derivative (Y. 70%, E/Z = 3 : 1). Z and E isomers are further separated by preparative TLC (methylene chloride : hexane = 10 : 1).

References


PubMed Literature


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