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CAS RN: 14694-95-2 | Product Number: T0931

Tris(triphenylphosphine)rhodium(I) Chloride


Purity: >98.0%(T)
Synonyms:
  • Chlorotris(triphenylphosphine)rhodium(I)
  • Wilkinson Catalyst
Documents:
1G
€50.00
11   ≥20 
5G
€179.00
1   12  

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Product Number T0931
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__5__4H__4__5ClP__3Rh = 925.23  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive
CAS RN 14694-95-2
Reaxys Registry Number 14664394
PubChem Substance ID 87576749
SDBS (AIST Spectral DB) 5193
Merck Index (14) 9758
MDL Number

MFCD00010016

Specifications
Appearance Orange to Brown to Dark red powder to crystal
Purity(Argentmetric Titration) min. 98.0 %
Properties (reference)
Solubility in water Insoluble
Solubility (soluble in) Toluene,Chloroform,Benzene,dichloromethane
Solubility (very slightly) Methanol
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws: / Compliance with laws, Regulations
Enzyme Commission 238-744-5
Transport Information:
HS Number 2843909000
Application
Trimethylsilylation of Alcohols using TMS Reagents

References

Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols

P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


Application
Wilkinson’s Catalyst: a Homogeneous Catalyst for Hydrogenation

References

1)Total synthesis of (+)-fusarisetin A

J. Huang, L. Fang, J. Gong, C. Li, Z. Yang, Tetrahedron 2015, 71, 3720.

2)Hydride Intermediates in Homogeneous Hydrogenation Reactions of Olefins and Acetylenes using Rhodium Catalysts

J. F. Young, J. A. Osborn, F. H. Jardine, G. Wilkinson, Chem. Commun. 1965, 131.

3)The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives

J. A. Osborn, F. H. Jardine, J. F. Young, G. Wilkinson, J. Chem. Soc. A 1966, 1711.


Application
Rh-catalyzed Coupling Reaction between THF and Olefins

References

K. Cao, Y.-J. Jiang, S.-Y. Zhang, C.-A. Fan, Y.-Q. Tu, Y.-J. Pan, Tetrahedron Lett. 2008, 49, 4652.


PubMed Literature


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