text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 131219-55-1 | Product Number: T1551

Tetrakis[N-phthaloyl-(S)-phenylalaninato]dirhodium Ethyl Acetate Adduct


Purity:
Synonyms:
  • Rh2(S-PTPA)4 EtOAc
  • Dirhodium Tetrakis[N-phthaloyl-(S)-phenylalaninate] Ethyl Acetate Adduct
Documents:
100MG
€269.00
5   2  

*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).


Product Number T1551
Molecular Formula / Molecular Weight C__6__8H__4__8N__4O__1__6Rh__2·C__4H__8O__2 = 1471.06  
Physical State (20 deg.C) Solid
CAS RN 131219-55-1
PubChem Substance ID 87577310
MDL Number

MFCD00191695

Specifications
Appearance Green to Dark green powder to crystal
Elemental analysis(Carbon) 57.60 to 60.00 %
Elemental analysis(Nitrogen) 3.70 to 3.90 %
Properties (reference)
GHS
Related Laws: / Compliance with laws, Regulations
Transport Information:
HS Number 2843909000
Application
A Useful Chiral Dirhodium(II) Complex Catalyst

Experimental procedure2): the bis(ethyl acetate) adduct of Rh2(S-PTPA)4 (32 mg, 0.021 mmol) is added in one portion to a stirred solution of the 1 (300 mg, 1.04 mmol) in dry dichloromethane (3 mL) at 22 °C under argon atmosphere. After 6 h of stirring at this temperature, the resultant greenish solution is concentrated in vacuo and purified by silica gel column chromatography (hexane:ethyl acetate = 3:1) to give 2 (yield 97%, 60% ee).

References


PubMed Literature


TCIMAIL
Documents
Safety Data Sheet (SDS) Search
Please select Language.

The requested SDS is not available.

• Please check that the Product Number you have entered is correct.

• If your information is correct and you are still not able to view the requested SDS,  please Contact Us for more information.

C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number is entered
Other Documents