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CAS RN: 55364-28-8 | Product Number: T2977
(E)-Trimethyl(3,3,3-trifluoro-1-propenyl)silane
Purity: >95.0%(GC)
Synonyms:
- Ikeda - Omote Reagent
Product Documents:
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| Product Number | T2977 |
Purity / Analysis Method
|
>95.0%(GC) |
| Molecular Formula / Molecular Weight | C__6H__1__1F__3Si = 168.23 |
| Physical State (20 deg.C) | Liquid |
Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 55364-28-8 |
| Reaxys Registry Number | 2411211 |
| PubChem Substance ID | 253660663 |
Specifications
| Appearance | Colorless to Light yellow clear liquid |
| Purity(GC) | min. 95.0 % |
Properties (reference)
| Boiling Point | 69 °C |
| Specific Gravity (20/20) | 0.95 |
| Refractive Index | 1.36 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H225 : Highly flammable liquid and vapour. |
| Precautionary Statements | P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 : Keep container tightly closed. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. |
Related Laws:
Transport Information:
| UN Number | UN1993 |
| Class | 3 |
| Packing Group | II |
| HS Number | 2931900090 |
Application
A New 3,3,3-trifluoropropenylation Reagent, Ikeda–Omote Reagent

References
- 1) 1,4‐Bis(alkenyl)‐2,5‐dipiperidinobenzenes: Minimal Fluorophores Exhibiting Highly Efficient Emission in the Solid State
- 2) Simple Synthesis of β-Trifluoromethylstyrenes Using (E)-Trimethyl-(3,3,3-trifluoroprop-1-enyl)silane
- 3) Synthesis of 2-Aryl-3-trifluoromethylquinolines Using (E)-Trimethyl(3,3,3-trifluoroprop-1-enyl)silane
- 4) Synthesis of Fluorinated Heterocycles Designed to Deliver the Modified Bioactive Behavior: Synthetic Use of Ethyl Bromodifluoroacetate, Ethyl Dibromofluoroacetate and Fluorine Containing Vinylsilanes
- 5) Oxidative 3,3,3-trifluoropropylation of arylaldehydes
- 6) One-pot synthesis of 1,3-enynes with a CF3 group on the terminal sp2 carbon by an oxidative Sonogashira cross-coupling reaction
PubMed Literature
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