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Published TCIMAIL newest issue No.198
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CAAC (Cyclic(Amino)(Alkyl)Carbene)-rhodium complexes are used as efficient and selective aromatic hydrogenation catalysts owning from their strongly σ-donating ligands. These catalysts can be used for the synthesis of cyclohexane moieties while still retaining various functional groups like carbonyls, silyls, and boryls in a single step. Under these conditions, the cis-configured saturated hydrocarbon is selectively given.
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Advantages
• Utilized in selective hydrogenation of aromatic rings in aromatic ketones
• Suitable for the conversion of phenols to cyclohexanones
• Effective in cis-selective hydrogenation of multisubstituted aromatic compounds
• Suitable for the conversion of phenols to cyclohexanones
• Effective in cis-selective hydrogenation of multisubstituted aromatic compounds
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References
- 1)Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes
- 2)Silylarene Hydrogenation: A Strategic Approach that Enables Direct Access to Versatile Silylated Saturated Carbo- and Heterocycles
- 3)Hydrogenation of Borylated Arenes
