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CAS RN: 1496636-80-6 | Product Number: B5360

N,N'-Bis(tert-butoxycarbonyl)-3-(trimethylsilyl)-2-propyne-1,1-diamine


Purity: >96.0%(GC)
Synonyms:
  • N,N'-Di-Boc-3-(trimethylsilyl)-2-propyne-1,1-diamine
  • Di-tert-butyl [3-(Trimethylsilyl)prop-2-yne-1,1-diyl]dicarbamate
  • [3-(Trimethylsilyl)prop-2-yne-1,1-diyl]dicarbamic Acid Di-tert-butyl Ester
Documents:
1G
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Product Number B5360
Purity / Analysis Method >96.0%(GC)
Molecular Formula / Molecular Weight C__1__6H__3__0N__2O__4Si = 342.51 
Physical State (20 deg.C) Solid
CAS RN 1496636-80-6
Reaxys Registry Number 23644991
Specifications
Purity(GC) min. 96.0 %
Properties (reference)
GHS
Related Laws:
Transport Information:
Air Transportation Airmail banned
Application
Boc-Alkynylimine Equivalent Useful for the Synthesis of Propargylamine Derivatives

Experimental procedure2): To a solution of 1 (0.10 mmol) and diphenyl phosphate (2.5 mg, 0.010 mmol) in dichloromethane (2.0 mL) is added 3-phenylpropanal (0.30 mmol) at room temperature. After 1 is consumed, the reaction mixture is added CH3OH (2.0 mL) and NaBH4 (11 mg, 0.30 mmol) at 0 °C. After stirring for 2 h at 0 °C, the reaction mixture is quenched with water and extracted with EtOAc. The combined organic layers are washed with brine, dried over Na2SO4 and concentrated. The residue is purified by column chromatography on silica gel (eluting with hexane:EtOAc = 7:1, then toluene:EtOAc = 20:1) to afford the corresponding aminoalcohol in 50% yield.

References


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