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CAS RN: 77-73-6 | Product Number: D0443
Dicyclopentadiene (stabilized with BHT) [precursor to Cyclopentadiene]
Purity: >97.0%(GC)
Chemical Substance Law (ENCS):
4-634
|Priority Assessment Chemical Substance
Synonyms:
- 3a,4,7,7a-Tetrahydro-4,7-methano-1H-indene (stabilized with BHT)
- Tricyclo[5.2.1.02,6]deca-3,8-diene (stabilized with BHT)
Documents:
Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
---|---|---|---|---|
25ML |
¥1,900
|
Contact Us | Contact Us | Contact Us |
500ML |
¥3,500
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≥40 | ≥40 | Contact Us |
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* Please contact us if you need further information.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Product Number | D0443 |
Purity / Analysis Method | >97.0%(GC) |
Molecular Formula / Molecular Weight | C__1__0H__1__2 = 132.21 |
Physical State (20 deg.C) | Solid |
CAS RN | 77-73-6 |
Related CAS RN | 542-92-7 |
Reaxys Registry Number | 1904092 |
PubChem Substance ID | 87567119 |
SDBS (AIST Spectral DB) | 4392 |
MDL Number | MFCD00078246 |
Specifications
Appearance | White or Colorless to Almost white or Almost colorless powder to lump to clear liquid |
Purity(GC) | min. 97.0 % |
Properties (reference)
Melting Point | 32 °C |
Boiling Point | 167 °C |
Flash point | 44 °C |
Refractive Index | 1.51 |
Solubility in water | Insoluble |
Degree of solubility in water | 40 mg/l |
Solubility (soluble in) | Alcohol,Toluene,Ether,Acetone,dichloromethane |
GHS
Pictogram |
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Signal Word | Danger |
Hazard Statements | H330 : Fatal if inhaled. H302 : Harmful if swallowed. H315 + H320 : Causes skin and eye irritation. H361 : Suspected of damaging fertility or the unborn child. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H373 : May cause damage to organs through prolonged or repeated exposure. H335 : May cause respiratory irritation. H304 : May be fatal if swallowed and enters airways. H411 : Toxic to aquatic life with long lasting effects. H228 : Flammable solid. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P201 : Obtain special instructions before use. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 : Collect spillage. P331 : Do NOT induce vomiting. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P405 : Store locked up. |
Related Laws:
Chemical Substance Law (ENCS) |
4-634 Priority Assessment Chemical Substance |
PRTR Law (New Specific Chemical) | Class 1 Designated Chemical Substances |
Fire Defense Law | Group-4-2-III |
RTECS# | PC1050000 |
Transport Information:
UN Number | UN2048 |
Class | 3 |
Packing Group | III |
Application
Precursor to Cyclopentadiene
Typical Procedure:The reaction apparatus is assembled by attaching a thermometer, Vigreaux distilling column and Liebig condenser to a 500 mL two necked flask. The receiver is cooled by means of refrigerants or freezing mixtures. Dicyclopentadiene (195 g) is placed in the two necked flask and heated to about 160 ℃ with an electric heating mantle or oil bath. Thermal decomposition begins at about 150 ℃ and distillates at 38~46 ℃ can be obtained (addition of iron powder expedites the thermal decomposition rate of cyclopentadiene). Heating is applied slowly, because rapid temperature increases cause dicyclopentadiene to distill prior to undergoing thermal decomposition. In such a case, re-distillation allows narrow boiling-point distillates. Cyclopentadiene dimerzes rapidly at room temperature and should be used immediately.
References
- Org. Synth. 1963, coll. Vol. 4, 238.
- Org. Synth. 1962, 42, 50.
PubMed Literature
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