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CAS RN: 62778-11-4 | Product Number: P0999
Pyridinium Poly(hydrogenfluoride) [Fluorinating Reagent]
![Pyridinium Poly(hydrogenfluoride) [Fluorinating Reagent] Chemical Structure of Pyridinium Poly(hydrogenfluoride) [Fluorinating Reagent]](/medias/P0999.jpg?context=bWFzdGVyfHJvb3R8NDE3ODJ8aW1hZ2UvanBlZ3xhRGd4TDJnMFlTODRPVEl5T1RBeU16WTBNVGt3TDFBd09UazVMbXB3Wnd8MWVkM2Q1YzNjMGQ2ODZlNmViOTRiYzc0NTNmYTUyMGM0ZWE1YmExMDc4Nzg2ZDgyNjk1NjkzOTZlNGRmYWVkMw)
Purity:
Poisonous substance
Synonyms:
- Hydrogen Fluoride-Pyridine
- Olah's Reagent
Product Documents:
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* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Product Number | P0999 |
Molecular Formula / Molecular Weight | C__5H__5N·(HF)__x |
Physical State (20 deg.C) | Liquid |
Storage Temperature ![]() |
Frozen (<0°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Moisture Sensitive,Heat Sensitive |
CAS RN | 62778-11-4 |
PubChem Substance ID | 87575112 |
Merck Index (14) | 6821 |
MDL Number | MFCD00012436 |
Specifications
Appearance | Colorless to Light yellow to Light orange clear liquid |
Content of HF(Neutralization titration) | min. 65.0 % |
Properties (reference)
Boiling Point | 50 °C/1 mmHg |
Specific Gravity (20/20) | 1.10 |
GHS
Pictogram |
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Signal Word | Danger |
Hazard Statements | H300 + H310 + H330 : Fatal if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H335 : May cause respiratory irritation. H290 : May be corrosive to metals. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P270 : Do not eat, drink or smoke when using this product. P262 : Do not get in eyes, on skin, or on clothing. P260 : Do not breathe mist or vapours. P234 : Keep only in original packaging. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P390 : Absorb spillage to prevent material damage. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P361 + P364 : Take off immediately all contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P406 : Store in a corrosion resistant container with a resistant inner liner. P405 : Store locked up. |
Related Laws:
ISHL |
Group 2 Substance |
PRTR Law (New Specific Chemical) | Class 1 Designated Chemical Substances |
Poisonous or Deleterious | Poisonous substance |
Transport Information:
UN Number | UN1790 |
Class | 8 / 6.1 |
Packing Group | I |
Application
Fluorination
References
- M. Hayashi, S. Hashimoto, R. Noyori, Chem. Lett. 1984, 1747.
- W. A. Szarek, G. Grynkiewicz, B. Doboszewski, G. W. Hay, ibid. 1984, 1751.
- A. Ourari, R. Condom, R. Guedj, Can. J. Chem. 1982, 60, 2707.
- G. A. Olah, G. K. S. Prakash, Y. L. Chao, Helv. Chim. Acta 1981, 64, 2528.
- G. A. Olah, J. T. Welch, Y. D. Vankar, M. Nojima, I. Kerekes, J. A. Olah, J. Org. Chem. 1979, 44, 3872.
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