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CAS RN: 2564-83-2 | Product Number: T1560

2,2,6,6-Tetramethylpiperidine 1-Oxyl Free Radical


Purity: >98.0%(GC)(T)
Synonyms:
  • TEMPO Free Radical
Documents:
5G
¥6,700
≥20  5   ≥20 
25G
¥20,000
≥20  6   ≥20 
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Product Number T1560
Purity / Analysis Method >98.0%(GC)(T)
Molecular Formula / Molecular Weight C__9H__1__8NO = 156.25  
Physical State (20 deg.C) Solid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Heat Sensitive
CAS RN 2564-83-2
Reaxys Registry Number 1422418
PubChem Substance ID 87577318
Merck Index (14) 9140
MDL Number

MFCD00009599

Specifications
Appearance Orange to Brown powder to crystal
Purity(GC) min. 98.0 %
Purity(Iodometric Titration) min. 98.0 %
Solubility in Methanol almost transparency
Properties (reference)
Melting Point 39 °C
Flash point 67 °C
Solubility (soluble in) Methanol
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dusts or mists.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P405 : Store locked up.
Related Laws:
Fire Defense Law Group-4-2-III
RTECS# TN8991900
Transport Information:
UN Number UN3263
Class 8
Packing Group II
Application
Nitroxyl-radical-catalyzed Oxidative Coupling of Amides with Silylated Nucleophiles

T1560

Typical Procedure:
To a solution of N-benzylbenzenesulfonamide (61.8 mg, 0.25 mmol), KBr (14.9 mg, 0.125 mmol), and Na2SO4 (71.0 mg, 0.50 mmol) in MeCN (1.5 mL) is added t-BuOCl (33.9 µL, 0.30 mmol) at room temperature, and the mixture is stirred at room temperature for 1 h. Then, TEMPO (7.8 mg, 0.050 mmol) is added and stirred at room temperature for 30 min. To the solution is added Na2CO3 (26.5 mg, 0.25 mmol), and the mixture is stirred at room temperature for 20 h. Subsequently, TMSCN (93.8 mL, 0.75 mmol) and LiClO4 (2.7 mg, 0.025 mmol) are added to the reaction mixture, and further stirred at room temperature for 22 h. Saturated Na2SO3 aqueous solution (10 mL) is added to the mixture, and the product is extracted with AcOEt (15 mL×3). The organic phase is washed with brine and dried over Na2SO4. The organic phase is concentrated under reduced pressure, and the crude product is purified by column chromatography (hexane : AcOEt = 3 : 1) to give the desired product (67.4 mg, Y. 99%).

References


Application
Catalytic Oxidation

References


PubMed Literature


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