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Naphtho[1,2-c:5,6-c']bis([1,2,5]thiadiazole) (NTz) structures (1-3) are useful electron-deficient type building blocks for organic semiconductors. Some donor–acceptor conjugated polymers containing the NTz structures exhibited better power conversion efficiency (PCE) compared with widely used 2,1,3-benzothiadiazole-based polymers in organic photovoltaic devices.1,2) In addition, several conjugated polymers exhibiting beyond 10% PCEs were reported in 2016.3)
References
1)Donor–acceptor conjugated polymer based on naphtho[1,2-c:5,6-c]bis[1,2,5]thiadiazole for high-performance polymer solar cells
3)Implication of fluorine atom on electronic properties, ordering structures, and photovoltaic performance in naphthobisthiadiazole-based semiconducting polymers
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