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CAS RN: 87-91-2 | Product Number: T0003
Diethyl L-(+)-Tartrate
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Purity: >98.0%(GC)
Synonyms:
- L-(+)-Tartaric Acid Diethyl Ester
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| Product Number | T0003 |
Purity / Analysis Method 
|
>98.0%(GC) |
| Molecular Formula / Molecular Weight | C__8H__1__4O__6 = 206.19 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 87-91-2 |
| Reaxys Registry Number | 1727145 |
| PubChem Substance ID | 87576029 |
| Merck Index (14) | 3855 |
| MDL Number | MFCD00009143 |
Specifications
| Appearance | Colorless to Light yellow clear liquid |
| Purity(GC) | min. 98.0 % |
| Specific rotation [a]20/D | +7.6 to +7.9 deg(neat) |
| EtOH | lt. 0.5 % |
| NMR | confirm to structure |
Properties (reference)
| Boiling Point | 280 °C |
| Flash point | 93 °C |
| Specific Gravity (20/20) | 1.21 |
| Specific Rotation | 7.8° (neat) |
| Refractive Index | 1.45 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H319 : Causes serious eye irritation. H360 : May damage fertility or the unborn child. H350 : May cause cancer. H227 : Combustible liquid. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P202 : Do not handle until all safety precautions have been read and understood. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403 : Store in a well-ventilated place. P405 : Store locked up. |
Related Laws:
Transport Information:
| H.S.code* | 2918.13-000 |
Application
Katsuki-Sharpless Asymmetric Epoxidation
References
- T. Katsuki, A. W. M. Lee, P. Ma, V. S. Martin, S. Masamune, K. B. Sharpless, D. Tuddenham, F. J. Walker, J. Org. Chem. 1982, 47, 1373.
- T. Katsuki, K. B. Sharpless, J. Am. Chem. Soc. 1980, 102, 5974.
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