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CAS RN: 16853-85-3 | Product Number: L0203
Lithium Aluminum Hydride (Powder)
×
Purity: >95.0%(T)
Synonyms:
- LAH (Powder)
Product Documents:
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|---|---|---|---|---|---|
| 25G |
$80.00
|
≥40 | 0 | It can be shipped in about 4-5 weeks after ordering | |
| 100G |
$240.00
|
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| Product Number | L0203 |
Purity / Analysis Method 
|
>95.0%(T) |
| Molecular Formula / Molecular Weight | LiAlH__4 = 37.95 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 16853-85-3 |
| Reaxys Registry Number | 11460447 |
| PubChem Substance ID | 87560001 |
| Merck Index (14) | 350 |
| MDL Number | MFCD00011075 |
Specifications
| Appearance | White to Gray powder to crystal |
| Purity(NBS Method) | min. 95.0 % |
Properties (reference)
| Melting Point | 125 °C(dec.) |
| Solubility (soluble in) | Tetrahydrofuran, Dioxane, Ether |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H330 : Fatal if inhaled. H301 : Toxic if swallowed. H314 : Causes severe skin burns and eye damage. H260 : In contact with water releases flammable gases which may ignite spontaneously. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P223 : Do not allow contact with water. P260 : Do not breathe dust. P270 : Do not eat, drink or smoke when using this product. P231 + P232 : Handle and store contents under inert gas. Protect from moisture. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P302 + P335 + P334 : IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P402 + P404 : Store in a dry place. Store in a closed container. P405 : Store locked up. |
Related Laws:
| RTECS# | BD0100000 |
Transport Information:
| UN Number | UN1410 |
| Class | 4.3 |
| Packing Group | I |
| H.S.code* | 2850.00-000 |
Application
Reducing Agent
References
- Communications Reduction of Acetals to Ethers by Means of Lithium Aluminum Hydride-Aluminum Chloride
- Selective reductions. 28. The fast reaction of lithium aluminum hydride with alkyl halides in tetrahydrofuran. A reappraisal of the scope of the reaction
- Asymmetric synthesis via axially dissymmetric molecules. 6. Rational designing of efficient chiral reducing agents. Highly enantioselective reduction of aromatic ketones by binaphthol-modified lithium aluminum hydride reagents
Application
Inorganic Hydride Used as A Hydrogen Sources of Fuel Cell
References
- Design for the cold start-up of a man-portable fuel cell and hydrogen storage system
- Development of hydrogen storage for fuel cell generators. I: Hydrogen generation using hydrolysis of hydrides
- Hydrogen generation from hydrides in millimeter scale reactors for micro proton exchange membrane fuel cell applications
PubMed Literature
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